Papers by Keyword: Salt-Assistant Combustion Method

Abstract: Ultrafine square-shaped pyrochlore-type Nd₂Sn₂O₇ nanocrystals were synthesized by a convenient salt-assisted combustion process using glycine as fuel. The products were characterized by X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), Raman spectroscopy, Transmission electron microscopy (TEM) and high-resolution transmission electron microscopy (HRTEM). The results indicate that the products are phase-pure nanocrystals with pyrochlore-type structure. TEM and HRTEM images reveal that the products are composed of well-dispersed square-shaped Nd₂Sn₂O₇ nanocrystals with the average size of 30 nm and the crystallite is structurally uniform and crystalline. The presented method provides a convenient and low-cost route for the synthesis of oxide materials nanostructures.

Abstract: Well-dispersed fluorite Er2Zr2O7 nanocrystals have been successfully prepared by a convenient salt-assistant combustion method. The effects of calcinations temperature and salt category on the characteristics of the products were investigated by XRD and TEM. The thermal treatment temperature has an important effect on crystal size and lattice distortion of the nanocrystals. The experiment showed that the introduction of salt in the combustion synthesis process resulted in the formation of well-dispersed Er2Zr2O7 nanocrystals. The average size was 30 nm and was in agreement with the XRD result, which indicated that the nanocrystals were uniform in particle size distribution. Moreover, the possible formation process in the salt-assisted combustion synthesis was also analyzed.

Abstract: Eu2Zr2O7 nanocrystals with cubic structure were successfully synthesized by salt-assistant combustion method. The Eu2Zr2O7 nanocrystals were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), and Emission/ excitation spectra. The effect of thermal treatment temperature on the crystal size of nanocrystals was studied. The results indicated that Eu2Zr2O7 nanocrystals obtained by this method were well-dispersed and uniform in particle size distribution with average size of 20 nm. By comparison, it was found that the introduction of KCl in the solution combustion reaction process can effectively prevent nanocrystallites from sintering and forming inseparable three-dimensional network, and result in the formation of well-dispersed nanoparticles. The method provides a convenient, low-cost and nontoxic route for the synthesis of nanostructures of oxide materials. Moreover, the strong fluorescent property of the Eu2Zr2O7 nanocrystals obtained by salt-assistant combustion method at 385 nm upon excitation was measured at room temperature. The results showed that Eu2Zr2O7 nanocrystals obtained by salt-assistant combustion method put up excellent fluorescent properties.