Papers by Keyword: Solution

Abstract: Today the prepreg technology for the manufacture of products from polymer composite materials is widely used in the global industry. This technology involves the use of prepregs obtained by preliminary impregnation of the reinforcing materials with binder solutions, which contain up to 50% environmentally sensitive and fire hazardous solvents. However, in many cases no systematic approach is used to solve the issues of choosing the optimal values of the solvent content in the binder solution to ensure its specified viscosity according, as well as the issues of safety of the industrial activity; instead, these issues are solved independently. It results in the unreasonable expense, loss of quality of the composite products and insufficient level of safety of production activity at the relevant workplaces. This study deals with the systematic prediction of the process parameters, taking into consideration the safety of operational procedures during the impregnation of prepregs and permissible range of deviations from their regulated value. The method and the relevant implementing technique for the prediction of optimal process parameters of the binder solutions for impregnation of prepregs in view of safety of the production activity have been developed. Dependences of the viscosity of the binder on its temperature and volume content of one-component, binary and three-component solvents have been obtained, with the tolerance band specified for the volume and weight contents of the solvent in the binder, which provides an acceptable deviation in the solution viscosity for the effective impregnation of prepreg. The paper proposes and substantiates the criterion of content of the binary solvent in the binder being optimal one in terms of process conditions. This criterion provides both the specified quality of impregnation of the reinforcing material and requirements for the safety of production activity. The actual hands-on examples are considered as related to the determination of optimal content of the binary solvent with the components for the specific binder and alcohol-acetone solvent. It is shown that the optimal weight concentration of acetone in the solvent is 0.085, with the solvent weight content in the mixture of 0.279. These parameters provide the maximum allowable concentration of solvent vapors, ensuring the safety of production activity. It should also be noted, that the solvent weight content differs by maximum 5% from the value required when using alcohol only, which provides high safety margin of the production activity.

Abstract: The article covers the research of the chemical and mineralogical compositions of mortars used in the construction of architectural monuments of Uzbekistan in the 9^th-12^th centuries, which is based on the study of chemical composition, X-ray and differential thermal analyzes. Comprehensive study of the building materials used in mentioned monuments will allow development of identical modified solutions to preserve the value of architectural monuments.

Abstract: The search for optimal conditions for the method of synthesis of copper (II) salts to create a unified one-step method for obtaining salts from natural raw materials was the purpose of this work. During the process of salt production, it is desirable that the product accumulates in the solid phase and is easily separated by phase separation methods. The study of the direct interaction of copper (II) oxide with acids in organic liquid media using a bead mill as a reactor and grinding agent of different nature showed that besides the usual places of localization of product that take place in practice, we can meet unusual places of localization of product, such as the surface of a foreign solid phase in the reactor zone, for example, the surface of the grinding agent, reactor elements, etc. It was found that in some cases, localization on a solid surface could be a favorable localization option in terms of the speed of the process. But it happens not always, because it requires specific methods of separation of film from surface, which can be very expensive. Often, the localization of the product on the solid surfaces is an extremely unfavorable localization option. It was found that different variants of product localization of interaction CuO with acids which were implemented in different proportions, prevented the creation of a unified method for producing salts in such systems

Abstract: Using the optimal solution and aging treatment for Ti-6Al-4V brazed by Ti-15Cu-15Ni and Ag-26.7Cu-4.5Ti fillers, the average shear strengths of the lap-joint interface are improved. And the average grain sizes and the average lengths of Widmanstätten structure are significantly smaller than that of post-brazed annealing. Both fillers specimens are examined to indicate the strengthening mechanism is to homogenize the microstructure of Ti-6Al-4V joints to simultaneously enhance the strength of joint braze and substrate.

Abstract: Currently, in non–ferrous metallurgy, hydrometallurgical methods are practiced for metal recovering from copper ore in addition to pyrometallurgy, for example, SX–EW (solvent extraction–electrowinning). Although this technology gives the opportunity to get cathode copper from oxidized ores without thermal impact on the material, it has several disadvantages, one of which is the formation of interphase suspension or “crud” in the extraction process. The interphase suspension impedes and worsens extraction process performances and carries away the large number of valuable components, such as extractant, diluent and copper–containing solution. At present, this interphase suspension is not recycled, instead it is drained from the extractor and stored. Interphase suspension recycling is a highly relevant problem of hydrometallurgical production.

Abstract: The purpose of this research is to investigate the corrosion resistance of 5052 aluminum alloy to increasing salinity in sea water. Salt spray chamber was used to measure and compare the corrosion rate of 5052 aluminum alloy with weight reduction method. The experiment was conducted by varying the three concentrations of NaCl solution to compare the corrosion rate of the metal. The test specimens used were aluminum alloy 5052 with length of 6 cm, width of 4 cm and thickness of 0.7 cm. The tests were carried out for 48 hours, aggressive NaCl solutions with concentrations of 3.5%, 4% and 5% were used as an artificial sea water corrosion medium and the temperature in the test chamber was maintained at 35 °C. Corrosion rate for 3.5% NaCl solution, 4% NaCl solution and 5% NaCl solution were 0.197 mm/year, 0.541 mm/year and 0.558 mm/year, respectively. The higher concentration leads to greater corrosion rate.

Abstract: The effects of heat treatment on microstructure and mechanical properties of Ti-38644 alloy were investigated by scanning electron microscope (SEM) and transmission electron microscopy (TEM) as well as uniaxial tensile test. The results show that when the solution temperature is lower than 845°C, the microstructure of Ti-38644 alloy is equiaxed β phase with the grain size of 20μm, and the tensile strength is about 960MPa. As raising solution temperature to 860°C, the grain size of Ti-38644 alloy increases to 100μm and the tensile strength decreased to 870MPa. There are a large number of secondary α phase precipitated from the grain boundaries and within grain of β phase undergoing aging treatment. Secondary α phase coarsens with increasing the aging temperature, leading to the decrease of tensile strength. After solution treatment at 815°C for 1.5h, water quenching plus aging at 520°C for 10h, air cooling, Ti-38644 alloy shows a better mechanical property with the tensile strength 1330MPa, elongation and reduction of area 10% and 45% respectively.

Abstract: MoO₃ film is successfully prepared by water bath heating method. The existence of Mo element in the MoO₃ solution is determined by infrared test. The characteristic peak of Mo element roughly appears within the range from 500 cm^–1 to 700 cm^–1.Then the MoO₃ peak is found appearing at the location of the 30°–40° using XRD, which proves the existence of MoO₃ in the solution. SEM observations indicate that the MoO₃ film is smooth as the reaction continues for 4 h. Finally, the results of light absorption test show that MoO₃ film has a good absorbency.

Abstract: Chromium depletion in AISI304 stainless steel can lead to intergranular corrosion due to temperature conditions and degree of deformation, and consequently to materials failure. The aim of this work is to study the effect of sensitization treatment on the corrosion resistance in AISI304 stainless steel after solution heat treatment at 1,000°C. Sensitization treatments were carried out at 670°C for 1 h, 2h, 5h and 10h in the electrical furnace. The intergranular corrosion resistance of the sensitized specimens was evaluated by double loop electrochemical potentiokinetic reactivation test. The microstructure of the specimens before and after the corrosion tests was observed through optical and scanning electron microscope. Solution treatment shows the dual structure, however, aging for 5 hours depicts the ditch structure. The ratio of current density increased as a function of aging time resulted in increase in the degree of sensitization.

Abstract: The effects of solution heat treatment of Al6Si2Cu aluminum alloy on incipient melting of θ-Al₂Cu phase have been investigated. Solution heat treatments, in this study, are applied to improve of mechanical properties through a single-step solution heat treatment. The microstructure of as-cast specimen represents a typical dendrite structure having a secondary dendrite arm spacing of 37um. In addition to the Al matrix, a large amount of coarsen eutectic Si, θ-Al₂Cu intermetallic phases and Fe-rich phases are identified. As the solution temperature increases, the Vickers's hardness increases up to 510°C and thereafter hardness decreases at the temperature of 520°C and 530°C. This hardness behavior may closely related with microstructural evolution such as solubility of alloying elements up to 510°C and also melting of θ-Al₂Cu intermetallic phases over 510°C in this study. Consequentially, the optimal single-step solution heat treatment temperature should be 510°C to improve mechanical property.