Papers by Keyword: Sono-Solidification

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Abstract: Hypereutectic Al-Si-Cu alloys which are typical light-weight wear-resistant materials, are required to improve the ductility as well as the strength and wear-resistance for the wider applications. Increase in amounts of primary silicon particles causes the modified wear-resistance of hypereutectic Al-Si-Cu alloys, however, it leads to the poor strength and ductility. It is known that dual phase steels composed of hetero-structure have succeeded to bring contradictory mechanical properties of high strength and ductility concurrently. In order to apply the idea of hetero-structure to hypereutectic Al-Si-Cu alloys for the achievement of high strength and ductility along with wear resistance, ultrasonic irradiation to molten metal during the solidification, which is named sono-solidification, was carried out from its molten state to just above the eutectic temperature. The sono-solidified Al-17Si-4Cu alloy is composed of hetero-structure, that is, hard primary silicon particles, soft non-equilibrium α-Al phase and eutectic region. Rheocasting was performed at just above the eutectic temperature with sono-solidified slurry to shape a disk specimen. After the rheocasting with modified sono-solidified slurry held for 45s at 570oC, the quantitative optical microscope observation exhibits that the microstructure is composed of 18area% of hard primary silicon particles and 57area% of soft α-Al phase, in contrast there exist only 5area% of primary silicon particles and no α-Al phase rheocast with normally solidified slurry. Hence the tensile tests of T6 treated rheocast specimens with modified sono-solidified slurry exhibit the improved strength and 5% of elongation, regardless of more than 3 times higher amounts of primary silicon particles compared to that rheocast with normally solidified slurry.
804
Abstract: Ultrasonic vibration has been applied to various molten metal processes owing to the functions of (a) improvement in wettability, (b) liquid adhesion at a vibrating end surface and (c) sono-solidification such as grain refinement. The present study is focused on the sono-solidification with acoustic cavitaion in hypereutectic Al-18mass%Si alloy. There appears an equilibrium microstructure composed of primary silicon and coupled eutectic -Al/Si phases in Al-18mass%Si alloy, however, non-equilibrium -Al grains develop along with the equilibrium phases through the sono-solidification. During the sono-solidification of Al-18mass%Si alloy, non-equilibrium -Al grains are recognized in the molten metal close to the ultrasonic radiator just before reaching the eutectic temperature of 577 oC in addition to the refined primary silicon particles. The appearance of -Al grains is understood through acoustic cavitation: ultrasound in molten Al-Si alloys exhibits two outstanding behaviors of cavitation bubbling and acoustic streaming. Firstly the de-coupled eutectic reaction, which is recognized in the solidified eutectic Al-Si alloy with severe stirring, causes divorced -Al grains by the acoustic streaming with cavitation. Secondly it is expected that high pressure of over 1 GPa generated by the collapse of cavitaion babbles leads to not only an increase in the eutectic temperature, but also higher silicon content at the eutectic point in Al-Si alloy. Consequently, non-equilibrium -Al grains are nucleated at collapsed cavitaion bubble sites, and they are characterized by higher silicon content compared with that of primary -Al grains in hypoeutectic Al-7masst%Si alloy.
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