Papers by Keyword: Starch

Abstract: Starch nanoparticles is one of the most recently developed starch products that have been used in plastic and food packaging applications. The aim of this study was to investigate the production of modified starch nanoparticles for active food packaging materials. Starch nanoparticles were fabricated via nanoprecipitation method and characterized by Particle Size Analyzer (PSA), Scanning Electron Microscopy (SEM), and Ultraviolet (UV)-visible (UV-Vis) spectrophotometry. The modification process was conducted by adding lemongrass oil as active ingredient under rapid stirring. The result showed that modified starch nanoparticles exhibited spherical particles with a diameter of approximately 300-400 nm. The present method for modification of starch nanoparticles may provide an alternative approach to increase the usability of starch from Beneng Taro as local produce in Banten Province.

Abstract: This work is based on an investigation study to develop bio-composite materials that are renewable, biodegradable, and environmentally safe. The fibers used in this work are extracted from the plant Ampelodesma Mauritanica, It is a wild plant that is produced in abundance in the Mediterranean regions. Through this work, an overview of Diss fibers was provided, developing bio-composite using different starch matrices reinforced by Diss fibers, and evaluate their mechanical behavior using Charpy-tests to determine standard test specimens to estimate Weibull parameters suitable for the composite using statistical methods based on Weibull distribution. The obtained results, it was found that the bio-composite starch/Diss 40% Glycerol and 5% fiber reinforcement (SG40/RF5) had better results compared to the rest of the bio-composite, The Charpy impact energy modulus was about 31.25 (KJ/m²), which is 2.1 times higher than that achieved Measured from SG40 matrix (40% glycerol), and 1.3 times higher than those fortified with 10% fiber SG40/RF10 (40% glycerol reinforcement 10% fiber), and the statistical study confirmed the distribution of the results obtained, especially Weibull, which has three parameters.

Abstract: The restoration, the protection, or the creation of earthen buildings require improving the mechanical strength of the material. The first way to do that is to use inorganic additives, but these additives change the structural properties of earth and have a high carbon footprint. In contrast, the other way to consolidate is the use of organic additives such as vegetal derivatives that rearrange the minerals in the earth, with the lowest carbon footprint as they are from waste management. After preliminary tests with ten different organic additives from traditional recipes, we found that wheat starch improves the earth strength up to 50 %. In this study, we related the mechanical strengthening to the physicochemical interactions between clays and starch. We focus on three clays that represent the three main groups of clays: kaolinite, illite and montmorillonite. For this study, we mainly focused on compressive test and rheological tests. We showed that the improvement of the mechanical strength with starch is depending on clay nature and their chemistry. Then, we can recommend formulations based on the earth nature for new sustainable buildings. Furthermore, we can understand why it was an interesting way to use starch as a strengthening agent in traditional recipes and how it could be used to repair and protect buildings made of earthen material.

Abstract: The study of lime-based systems is vital to the design of new sustainable building materials. Air lime (calcium hydroxide, Ca (OH)₂) is a binder that has attracted considerable attention for its ability to capture CO₂ from the atmosphere, its low-cost and low-energy production process. Furthermore, Ca (OH)₂ is an important phase of hydrated Portland cements, and lime-based mortars have shown high elasticity and the ability of self-healing. The performance of lime-based building materials can be enhanced by the addition of organic compounds that can modify the mineralogy and microstructure of Ca (OH)₂. In this study, the effects of four biopolymers including starch, inulin, pectin, and calcium lignosulfonate, on the microstructure and mineralogy of lime have been investigated. Hydrated lime was produced by slaking quicklime in water. Two sets of hydrated lime batches were produced for each polymer: (i) the polymer was previously dissolved in water and subsequently mixed with lime, and (ii) the polymer was added as a dry powder to the already hydrated lime at the end of the slaking process. Characterisation of the batches was performed using scanning electron microscopy, X-ray diffraction and laser diffraction. Results indicate that biopolymers affect the nucleation and growth of Ca (OH)₂ crystals. This influences the microstructure and crystal aggregation of hydrated lime in colloidal suspension, which will have important implications on the use of biopolymers in Portland cement applications and in the use of lime as a binder for mortars.

Abstract: Calcium carbonate is so hard to be further developed in polymer applications because it is difficult to combine with other materials. Starch-coated calcium carbonate was prepared by using starch as the main modifier and sodium stearate and sodium hexametaphosphate as the auxiliary modifiers. Optimal modification conditions were tested by single factor experiment and orthogonal experiment optimization. Manifestation was evaluated with the help of Fourier infrared spectrometer (FT-IR) and laser particle size analyzer and other test instruments. Results showed that a starch film was successfully coated on the surface of calcium carbonate, and the edges and corners of the modified coated calcium carbonate were passivated, and the particles were rounded. The active interface calcium carbonate has a broad application prospect in the field of degradable biomaterials.

Abstract: A technique for starch modification by graft polymerization of acrylamide has been developed. The obtained copolymer is soluble in a wide range of pH 2 - 12. The modification of starch made it possible to freely combine it with aqueous acid solutions of chitosan, in order to achieve a synergistic effect of their properties. A porous material based on modified starch and its mixtures with chitosan, which has high sorption characteristics, has been developed. The resulting material is promising as a sorbent of heavy metal ions and packing materials for transportation and storage.

Abstract: In this study, the modification of starch was conducted through graft copolymerization of cinnamic acid to result in starch-g-poly(cinnamic acid). The cinnamic acid polymerization was carried out via radical polymerization using cerium ammonium nitrate (CAN) as an initiator. The viscosity of the graft copolymer 10000 ppm dissolved in 16% NaOH solution was measured at a temperature range of 25-75 °C. The results showed that the higher the temperature the lower the viscosity. The activation energy of viscous flow for the copolymer was 18.4 kJ.mol^-1. The viscosity values of the copolymer solutions were also measured in saline solutions with NaCl contents of 3−20%(w/v). For the measurements in these saline solutions, the highest viscosity was 3.39 cP at room temperature for the copolymer solution containing 5%(w/v) NaCl.

Abstract: In this study, the chemical modification of starch was conducted using itaconic anhydride as an esterifying agent. The results showed that sulphuric acid is more effective as a catalyst for esterification of starch compared to sodium hydroxide. The presence of attached itaconic anhyride in the starch affected the thermal behaviour and crystallinity of the resulting products as shown by the TGA, DSC, and the XRD data. In addition, the SEM micrographs also indicated that the modified starch exhibited a unique morphology in the form of block with different sizes ranging from 1 to 20 μm in length.

Abstract: Nowadays, the use of additions in the concrete blends to improve its behavior is increasingly noticeable. The present research describes the effect of adding a polymer to a concrete blend of materials belonging to the zone of Morelia, Mexico. The polymer is an organic starch gained commercially, and it was added at a 2 percent per cement weight. The concrete’s physical and mechanical performance was monitored against a control blend to quantify any improvements. Destructive and non-destructive tests were performed. The addition of a polymer improved substantial concrete performance. Numerical models found correlations among the tests made, a technique by machine learning for establishing predictive models to assess the results.

Abstract: We presented a scientific review of the literature on known biodegradable polymer composite materials and summarized the data on the effect of starch and thermoplastic starch on the biodegradability of industrially produced polymers. We considered the main starch plasticizers.