Papers by Keyword: Supersaturated Solid Solution

Abstract: In this article, the microstructural peculiarities and properties of dispersion-hardened beryllium bronze with Ni and Ti are studied after quenching (780 °C) in a supersaturated solid solution and aging (320 °C, 3h). Decomposition of the α-solid solution matrix is implemented by means of an intermittent reaction with a primary allocation intermetallic χ-phase (type Be₁₂Ti) with a VCT-lattice. It is shown that the strength properties (yield strength, micro-hardness) of the alloy more than double after aging.

Abstract: Multi-scale microstructure observation and three dimensional finite element thermal analysis of AlSi10Mg alloy fabricated by selective laser melting (SLM) process were demonstrated in order to understand the microstructure formation process during SLM fabrication. The unique hierarchically microstructures were observed: (1) the “fish scale” microstructure corresponding to a part of molten pool consists of columnar and equiaxed grains and (2) these grains contain a substructure of α-Al surrounded by Si particles. It is revealed that a supersaturated Si concentration due to the predicted rapid cooling rate on the order of 10⁶ oC/s. In addition, the base temperature during the fabrication increases gradually with some peak temperature of each laser path as the laser scan has proceeded on a powder layer. Although the thermal changes cause no melting of the AlSi10Mg except directly fused region by selective laser so called molten pool, those are capable of causing precipitation and/or clustering.

Abstract: Al-Si alloy was widely applied in automobile engine parts to realize weight reduction. The influence of casting temperature on the microstructure of die casting Al-Si-Cu-Mg alloy was studied in this paper. Based on ZL 101 alloy, the strength was improved with addition of 0.8% Cu element. The influence of pouring temperature on microstructure was investigated using optical microscope and electron probe micro-analysis (EPMA), and T1 heat treatment was optimized. The primary α-Al was more coarsened when the pouring temperature rose from 660 ̊C to 690 ̊C. The solid solubility of Cu in α-Al was 0.2406 wt%, analyzed by EPMA. Considering the solid solubility of Cu and avoiding porosity at high-temperature, T1 heat treatment was reasonable and affective. The micro-hardness reached to a peak value of 114 HV during aging at a temperature of 175 ̊C after 10 h. Therefore, 175 ̊C×10h aging was the most appropriate heat treatment process.

Abstract: High-silicon aluminum alloys as light-weight structural materials are attractive because of their high wear resistance, low density and low thermal expansion. However, the Si phase in the high-silicon aluminum alloys always has big size, which deteriorates the mechanical properties and machinability of alloys. In this paper, alloy ribbon of high-silicon aluminum alloy with the composition of Al₇₀Si₃₀ was prepared by melt-spinning method. Then alloy ribbon was broken to powder by ball milling. The alloy powers were consolidated by spark plasma sintering (SPS) at different sintering parameters including time and temperature under vacuum atmosphere. The density, hardness and compression property of the compacts were investigated. The sintered samples were characterized by scanning electron microscopy (SEM) and X-ray diffractometry (XRD), and compared with their alloy power and original alloy ribbons. The results showed that the density of Al₇₀Si₃₀ alloy, prepared under the condition of 320 °C and 500 MPa, was above 98%, the grain size was refined to sub-micron, and the wear resistance was good, micro-hardness was 311.70 Hv. It is believed that the existence of local high temperature and discharge plasma can break down and disrupt oxidation film on powder surface, and therefore improving the efficiency of sintering. In the case of large current, short time and low temperature, sintering grain growth was not obvious, there was less supersaturated solid solution precipitation and the rapid solidification microstructure , and the properties can be preferably reserved.

Abstract: C/Cu self-lubricating composites were a kind of potentially functional materials. Nanostructured C/Cu composites were prepared by the new technology of mechanical activation-spark plasma sintering (MA-SPS). Microstructures of the as-milled powder and the as-sintered simple were characterized by transmission electron microscopy (TEM) and X-ray diffraction (XRD), respectively. These investigations indicated that in Cu-C immiscible system, the nanostructured supersaturated solid solution of carbon in copper was formed at atomic level after milling for 24 h. Microstructures of SPS sintered C/Cu composites still kept the nanostructure. In addition, Cu-C interface bonding was good. It was ascribed to a double activation mechanism in the MA-SPS process, which improved the sintering activity of C/Cu powders. Nanostructured C/Cu composites were obtained by SPS sintered at 600 °C for 3 min.

Abstract: High current pulsed electron beam (HCPEB), a novel high-power energetic beam technology, has been developed as a useful tool for surface modification of materials. In the present work, the effect of HCPEB treatment on microstructure and wear resistance of Al-15Si and ZK60-1Y Mg alloys was investigated. The results show that a supersaturated solid solution of (Al) and (Mg) is formed on top surface of melted layer induced by rapid heating and cooling during HCPEB process. In addition, the melted layer of approximately 5~11μm thickness is obtained on the ZK60-1Y Mg alloy surface. Wear resistance of Al-15Si and ZK60-1Y Mg alloys are significantly improved after HCPEB treatment. It is demonstrated that HCPEB technology has a good application future in enhancing surface properties of Al-Si and Mg alloys.

Abstract: We review the current development status of Mo-Si-B alloys consisting of Mo solid solution and the intermetallic phases Mo3Si and Mo5SiB2 which could take advantage of the beneficial oxidation resistance of the silicide phases and of the outstanding mechanical properties of molybdenum. For adequate low temperature toughness a continuous Mo solid solution matrix should be established in the microstructure. Besides, wrought processing of such alloys at elevated temperatures requires the presence of an ultra-fine grained (UFG) microstructure. Both the prerequisites can be fulfilled using mechanical alloying (MA) as the crucial processing step which even yields nanostructured supersaturated powders after milling. However, values for the ductile-to-brittle transition temperature (DBTT) close to room temperature are unlikely due to grain boundary embrittlement by Si segregation. The possibility of reducing this segregation tendency by various micro-alloying additions will be demonstrated. Finally, the high temperature deformation behaviour of these UFG materials will be comparatively assessed against state-of-the-art Nickelbase single-crystalline superalloys.

Abstract: Pure Al (99%) and pure Fe (99.5%) sheets were mutually stacked and severely deformed up to equivalent strain of 16 by the accumulative roll bonding (ARB) process in an attempt to achieve bulk mechanical alloying. The deformation was carried out at RT. The Al/Fe sheets ARB processed by 1 cycle showed a number of shear bands penetrating the stacked layers. The Fe layers, which were harder than the Al layers, were subdivided by the shear bands into diamond-shaped regions. Dissolution of Fe into Al was observed and a supersaturated solid solution was formed in the specimen ARB processed by 10 cycles. It was also found that local amorphization occurred at interface regions via formation of Al5Fe2 intermetallic compound.

Abstract: The effect of the supersaturated solid solution decomposition occurring prior to, during, and after severe plastic deformation by torsion under high hydrostatic pressure on strengthening is examined by the examples of Al-Cu-Mg, Al-Mg-Sc, and Mg-Sm alloys and 0.12%C-0.85%Mn- 0.65%Si and 0,1%C-1.12%Mn-0.08%V-0.07%Ti low-carbon steels. The decomposition of the supersaturated solid solution was realized upon cooling from the quenching temperature (lowcarbon steels), prior to deformation (Al-Cu-Mg-, Mg-Sm alloys), during deformation (Al-Cu-Mg-, Mg-Sm alloys), and after deformation. It is shown, the decomposition of the supersaturated solid solution is effective for the grain refinement down to nanoscale and strengthening, but, for different materials, different combinations with SPD should be used.