Papers by Keyword: Surface Morphology

Abstract: This research study was focused on the effect of heat treatment on the isothermal oxidation of Fe-33Ni-18Cr alloy at 1000 °C. The Fe-33Ni-18Cr alloy was undergone heat treatment at three different temperatures, namely 1000 °C, 1100 °C and 1200 °C for 3 hours soaking time followed by water quench to vary the grain size of the alloy. The heat-treated alloys was prepared for further isothermal oxidation test. The heat-treated alloys was ground by using several grit of silicon carbide papers as well as weighed by using analytical balance and measured by using Vernier caliper before the oxidation test. The heat-treated Fe-33Ni-18Cr alloys was isothermally oxidized at 1000 °C for 150 hours exposure time. The characterization of the oxidized samples was carried out using optical microscope and scanning electron microscope (SEM). The heat treatment result shows that, increasing the heat treatment temperature was increased the average grain size of the alloy. The kinetics of oxidation was followed the parabolic rate law which represent the diffusion-controlled oxide growth rate. Fine grain structure of 1000i-1000 sample shows minimum weight gain and lower oxidation rate compared to samples of 1000i-1100 and 1000i-1200. On the other hand, 1000i-1100 and 1000i-1200 samples indicate the formation of oxide spallation and crack propagation on the oxidized surface, respectively.

Abstract: This research study describes the influence of different heat treatment temperature on isothermal oxidation of Fe-33Ni-18Cr alloy. The Fe-33Ni-18Cr alloy was undergone heat treatment at three different temperatures, namely 1000 °C, 1100 °C and 1200 °C for 3h soaking time followed by water quench to vary the grain size of the alloy. This alloy was ground by using several grit of silicon carbide papers as well as weighed by using analytical balance and measured by using Vernier caliper before oxidation test. The heat-treated Fe-33Ni-18Cr alloy was isothermally oxidized at 800 °C for 150h. The characterization of oxidized samples was carried out using optical microscope, scanning electron microscope equipped with energy dispersive x-ray (SEM-EDX) and x-ray diffraction (XRD). The results showed that, increasing the heat treatment temperature was increased the average grain size. The kinetics of oxidation followed the parabolic rate law which represents diffusion-controlled oxide growth rate. Fine grain structure of 1000 °C sample shows minimum weight gain and lower oxidation rate compared to samples of 1100 °C and 1200 °C that indicated oxide spallation and porous structure. Besides, phase analysis showed that the oxidized sample formed several oxide phases.

Abstract: The modification and tailoring characteristic of nanostructured materials are of great interest due to controllable and unusual inherent properties in such materials. Cobalt-doped zinc oxide (Co:ZnO) thin films were prepared using the sol-gel technique with the spin coating method. The optical and physical properties of Co:ZnO films were tailored by the adjustment of Co concentration, which was realised by varying the ratio. The morphology and structure properties were characterised, and the effects of Co doping and post-annealing were investigated. Similar with undoped ZnO, the synthesised Co:ZnO films have a hexagonal wurtzite structure with the crystallinity deteriorated, and present high visible transparency with the absorption edge redshifted. Debye–Scherrer analysis of XRD pattern reveals an increase of the crystallite size with doping concentration. The bandgap, calculated using a Tauc Plot method, reveals a decrease in the absorption onset with an increase in the doping level.

Abstract: The different initial morphologies of polished surface is one of the important factors affecting the quality of laser polishing. In order to investigate the flow characteristics of the molten pool with different morphologies, a two-dimensional (2D) axisymmetric numerical model is established based on the COMSOL software. The nonisothermal flow interface is used to couple the heat transfer and fluid flow, and simulate the evolution process of the molten pool with three different surface morphologies. The results show that the initial shape is a smooth plane, the flow velocity of the molten pool is stable and always in thermocapillary regime, then the protrusions were generated at the edge of the molten pool. Likewise, with the increase of the surface curvature, the capillary becomes the main driving force to eliminate the surface asperities. While the flow velocity and instability of the molten pool enhance, and the depth of the molten pool increases with the heat transfer generated by the mass flow along the z-axis direction.

Abstract: According to the observation of a metallurgical microscope, surface morphology of 2219 aluminium alloy under several corrosion circumstances, such as corrosion pits and grain boundary corrosion, is directly perceived. Furthermore, with a laser range finder, corrosion depth data can be measured, and by using some methods of data processing, the affection for this material of certain solution components and immersion time is studied quantitatively. This binary study mean not only provides both graphical and statistical analysis, but also gives the relationship between them, which makes the result more reliable.

Abstract: In this research, CoFe_2-xLa_xO₄-based smart magnetic material has been developed which will be applied as a microwave absorbing material. This smart magnetic material is an artificial advanced material which has properties such as electromagnetic waves so that it is able to respond to the presence of microwaves through the mechanism of spin electron resonance and wall resonance domain. This smart magnetic material consists of a combination of rare earth metal elements (spin magnetic in the f orbital configuration) and transition metal elements (spin magnetic in the d orbital configuration) with a semi-hard magnetic structure. This semi-hard is a characteristic of magnetic properties which is between hard magnetic and soft magnetic properties. This characteristic of the semi-hard magnetic properties is needed so that this material has the ability to absorb microwaves. Substitution of lanthanum into cobalt ferrite CoFe_2-xLa_xO₄ for La³⁺ (x = 0 - 0.8) has been synthesized using the solid reaction method through mechanical deformation techniques. The refinement result of X-ray diffraction shows that the sample contains 2 phases with increasing of x compositions. Particle morphology and elementary analysis were observed respectively by using a scanning electron microscope (SEM) and energy dispersive spectroscopy (EDS). It was concluded that the effect of La substitution on CoFe_2-xLa_xO₄ resulted in changes in the crystal structure parameters and phase transformation as a function of composition.

Abstract: The further evidence is presented for the phenomenon existence of the electrochemical phase formation of metals and alloys through the stage of the overcooled liquid state. An idea is proposed about the possible occurrence of wave-like shapes on the surface of metal deposits, electrodepositing under weak force impact. First it was predicted and then revealed experimentally, a wave-like vibration of a solidifying surface of the metal being electrodeposited in the form of ripples or choppiness under the weak force impact in parallel to the crystallization front. A mathematical model has been obtained describing the liquid state behaviour of metals being electrodeposited under the impact of centrifugal force on the annular plate. The generalized Maxwell model was used as the basic rheological equation of a state. The difference between the results obtained is testified when considering Newtonian and non-Newtonian (power-law) liquid. The software blocks for solving the obtained mathematical model, based on the MathCAD package, have been developed.

Abstract: Plasma is generally used for the doping of semiconductors. During plasma doping process, plasma interacts with the surface of semiconductor. As a result, defects are induced in the surface region. In this work, the surface morphology and roughness of silicon wafer caused by plasma treatment is studied by use of atom force microscope (AFM). It is found that, during the plasma process, each of the processing time of plasma, location of silicon wafer in plasma and the way of placement of silicon wafer has an influence on the surface morphology and roughness and the reason is discussed. The interaction between plasma and the surface of silicon wafer is qualitatively discussed.

Abstract: Plasma electrolytic oxidation (PEO) is a technique employed to significantly enhance the corrosion and tribological properties of the materials by forming an oxide ceramic film on the surface of the material. In this investigation, ZM21 Mg alloy was subjected to PEO treatment in silicate and phosphate-based aqueous solutions of 5grams and 10 grams per liter concentrations. The oxide film was characterized using SEM, profilometer, thickness meter, and polarization test. Results showed that the oxide film obtained with 10g/L phosphate-based solution offers higher corrosion resistance than the oxide films formed with other solutions.

Abstract: We report on antibacterial activities of Zinc oxide (ZnO) with different structures. Fast furrier transform infrared spectroscopy ZnO nanostructures showed peaks in the range between 450–600 cm-1 indicating the successful growth through the presence of Zn-O stretching. On the other hand, impurities such as zinc complexes might be present due to the appearance of peaks at 1110 cm-1, 1390 cm-1 and 1506 cm-1. Furthermore, SEM images revealed that nanorods and sea-urchin like nanostructures are present in the produced ZnO nanostructures. Nanorods exhibit a better antibacterial response than the sea-urchin like structure. The change in structural morphology along with its purity has greatly influenced the area of bacterial inhibition zone during antibacterial testing.