Papers by Keyword: Surface Structuring

Abstract: Local electrical properties of a 4H-Silicon Carbide SiC(0001) 4°off macrostepped surface, obtained after liquid Si melting in a SiC/Si/SiC sandwich configuration, are investigated by Atomic Force Microscopy (AFM) in both DC and RF modes. On the same sample, macrosteps that are wide enough for allowing spatial resolution of the signal from terraces and step risers, but also some unreacted areas with standard flat surface (without macrosteps) are characterized. Scanning Spreading Resistance (SSRM, DC mode) reveals homogeneous conductivity on the wide terraces of the 4H-SiC(0001) macrosteps. On unreacted areas, which contain many step risers, the resistance is found higher than on the wide terrasses but it is also noisier. In addition, the AFM-RF scanning Microwave Impedance Microscopy (sMIM) mapping confirms the previous results by revealing lower conductivity on the unreacted areas than on the terraces of the macrosteps. Based on these results, some points defects located at the step risers which contribute negatively to the electrical properties of 4H-SiC(0001) surface are identified and electrically characterized.

Abstract: Methods of laser treatment and oxygen plasma treatment for the anti-reflective coatings on the basis of composite materials filled by epoxy polymer with multi-walled carbon nanotubes are demonstrated. The influence of structuring the surface of composite materials by different methods on the reflectivity in the UV, visible, near and middle IR wavelength ranges has been investigated. The possibility of creating composite structures with low reflectance in the range of 0.2 - 25 µm, corresponding to the requirements for anti-reflection coatings of optical and optoelectronic systems of spacecraft and ground-based systems, has been demonstrated.

Abstract: Mesa- and trench-patterned surfaces of 4H-SiC(0001) 4°off wafers were structured in macrosteps using Si melting in a SiC-Si-SiC sandwich configuration. Si spreading difficulties were observed in the case of trench-patterned samples while the attempts on mesa-patterned ones were more successful. In the latter case, parallel macrosteps were formed on both the dry-etched and unetched areas though these macrosteps rarely cross the patterns edges. The proposed mechanism involved preferential etching at Si-C bilayer step edges and fast lateral propagation along the [1120] direction.

Abstract: The reconstruction of 4°off 4H-SiC surfaces was investigated using Si melting at 1550°C in a SiC/Si/SiC sandwich configuration. Despite systematically obtaining a macrostepped morphology over the entire areas in contact with the liquid Si, the steps were found wavy when using as-received 4H-SiC wafers. The regularity and straightness of the steps were significantly improved when the surface reconstruction was performed on processed surfaces: on re-polished surfaces the steps were found to be regular and straight in some cases, while this was constantly observed on as-grown epitaxial layers. After a reconstruction process of 2h, the best regularity of the steps was obtained with an average width of ̴ 3-5 μm. Increasing the processed area from 1.44 to 4 cm² did not affect the results which suggests a good scalability of the process.

Abstract: Icing, the phenomenon of the formation and accumulation of ice or frost on a surface due to the solidification of water droplets at low temperature can be undesirable in many applications. Surface icing can lead to increased energy consumption in aerospace and automotive applications due to increased aerodynamic drag. Ice formation can also present a mechanical and electrical safety hazard, and as such significant work has been done to produce surfaces with anti-icing properties through surface modification to decrease ice formation and adhesion to surfaces. One route toward the generation of anti-icing surfaces is through laser surface processing. Laser micro/nanostructuring of surfaces has advanced greatly in recent years due to advancements in laser source technology and reduction in capital costs for ultrafast femtosecond pulsed machining lasers. Laser material processing offers a rapid, scalable, and non-contact method for fabricating large area anti-icing surfaces. In this work, the production of anti-icing surfaces using femtosecond laser micro-and nanostructuring on aluminum alloy 7075 surfaces was examined. With an aim to optimize the anti-icing properties of the substrates, laser parameters such as pulse energy, repetition rate and beam scanning speed were varied to produce highly defined microstructures on the aluminum surface.Various functional properties such as hydrophobicity and surface roughness are examined.

Abstract: In view of obtaining a step bunched morphology on large 4H-SiC surfaces, a sandwich configuration is investigated. A piece of silicon is melted between two 4H-SiC 4° off wafers, allowing a better spreading of the liquid than a Si drop approach. This successfully leads to highly step-bunched surfaces, though with irregular steps. The most regular step and terrace stuctures were found to be the result of epitaxial growth via a dissolution-precipitation process occuring from the edges to the center of the wafers. This is probably caused by radio-frequency induced electromagnetic convection within liquid Si. This process is quenched when using smaller liquid thickness.

Abstract: In the automotive industry, the development of electrically powered vehicles has become a major forward-looking topic. For improving the range and thus the efficiency of electric cars, lightweight construction has gained even more importance. In this regard, hot stamping has been established as a suitable and resource efficient process to manufacture high-strength and lightweight body-in-white components. This method combines hot forming and quenching of boron-manganese steel 22MnB5 in a single process step. As a result, complex structures with thin sheet thicknesses and high ultimate tensile strength up to 1500 MPa are generated. However, the use of lubricants is not possible at elevated temperatures, which subsequently leads to high thermo-mechanical tool stresses. As a side effect, high friction and severe wear occur during the forming process, which affect the resulting part quality and maximum tool life. Therefore, the aim of this study is to improve the tribological performance of hot stamping tools by using a laser implantation process. This technique is based on manufacturing highly wear resistant, separated and elevated structures in micrometer range by embedding hard ceramic particles into the tool material via pulsed laser radiation. As a result, highly stressed areas on the tool surface can be modified locally, which in turn influence the tribological and thermal behavior during the forming process. In this regard, laser implanted and conventionally tool surfaces were investigated under hot stamping conditions. A modified pin-on-disk test was used to analyze the friction coefficient and occuring wear mechanisms. Furthermore, quenching tests as well as hardness measurements were carried out to gain in-depth knowledge about the cooling behavior of the modified tool surfaces and its impact to the resulting mechanical part properties.

Abstract: Micrometric surface topologies are required for a wide range of technical applications. While lowered surface features have been used for many years to improve the tribological behavior of contacting surfaces, there are also other fields of application, where the potential of elevated surface features is known, e. g. for metal forming tools. However, the demand for a high wear resistance of these structures often inhibits an industrial application. A solution is offered by structuring techniques that use additional material. A promising approach is the localized dispersing of hard ceramic particles by pulsed laser radiation, the so-called laser implantation. This paper describes the potential to adjust the geometry as well as the mechanical properties of laser implanted surfaces by means of microstructural and topological investigations. Afterwards, results of a wear test are given and different applications for this structuring technique are discussed. It can be shown that dome-shaped or ring-shaped structures on a micrometric scale can be produced with high hardness and wear resistance.

Abstract: Electrophoretic deposition of ligand-free platinum nanoparticles has been studied to elucidate how wettability, indicated by contact angle measurements, is linked to vital parameters of the electrophoretic deposition process. These parameters, namely the colloid concentration, electric field strength and deposition time, have been systematically varied in order to determine their influence on the contact angle. Additionally, scanning electron microscopy has been used to confirm the homogeneity of the achieved coatings.

Abstract: In aeronautics, economic and environmental aspects become increasingly important. As those are very much influenced by the frictional drag of the airplane, a reduction of skin friction which causes a major portion of total aerodynamic drag is desirable. One possible approach for passive drag reduction is the application of riblets small longitudinal grooves orientated in flow direction. Through an adapted rolling process, riblets can be brought into metal sheets on a large scale. For this process a thin high-strength steel wire is wound around a work roll to structure it with the negative riblet imprint. In a subsequent step the riblet profile is rolled into the sheet material. Different parameters can influence the process and the quality of the resulting riblet structure. Those parameters that depend on the sheets sheet thickness, material strength, and composition of the sheet are discussed in this paper. Form filling is used as an indicator for riblet quality. It is found that decreasing sheet thickness is beneficial for form filling, but a process dependent minimum sheet thickness exists for which this effect will reverse. Material strength is found to have a much smaller influence on form filling. Nevertheless, harder alloys seem to need a slightly smaller thickness reduction, but higher rolling forces and pressures to achieve desired form filling. Using clad instead of bare materials has a positive influence on form filling and riblet structuring. Furthermore, riblet rolling does not reduce the fatigue strength of the clad material.