Authors: Jing Lin, Cheng Zheng, Shu Xuan Qian, Xian Fang Cai, Yong Shun Lan, Dong Ming Zhang, Jia Wei Zhuang
Abstract: In this study, three polyurethane systems A (A450/RD181/L75), B(A450/RD181/N3390) and C(A450/RD181/2104/N3390) for in-mould decoration ink were studied. The results of thermogravimetric analysis showed that introducing rosin modified phenolic resin 2104 (RMPR) and N3390 into PU system A can improve the thermal stability, Moreover, Measurements of gel fraction and swell ratio showed that incorporation of N3390 is benificial for increasing the cross-linking density of PU systems as compared to L75 so as to increase the gel fraction and decrease the swell ratio.The tensile strength of cured PU systems increased following in the order: A
850
Authors: Qiang Xiao, Wen Fa Xiao, Xin Xin Liu, Li Tao Dong
Abstract: A novel cement fluid loss additive P1301, which can resist high temperature and high salt content, was synthesized using the monomers of 2-acrylamido-2-methyl-propane sulphonic acid (AMPS), acrylic acid (AA), acrylamide (AM) and n-vinyl-2-pyrrolidone (NVP) by the method of aqueous solution polymerization. Through the orthogonal experiment find the optimum process: the ratio of monomers AMPS: AA: AM: NVP at 4:3:2:1, reaction PH at 11, reaction temperature at 60°C and reaction time about 4 hours. The IR spectrum show that the polymer with the structure of all the monomers. The aging test, thermal performance test and the fluid loss performance testing show that the forpolymers P1301 has an excellent thermal stability that can be used in 240°Cand strong salt tolerance. The fluid loss additive P1301 has an excellent tolerance to salt and high temperature.
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Authors: Yan Wang, Guang Yang, Qian Peng, Pei Xiang Lu
Abstract: Lithium secondary batteries using LiNi0.5Mn1.5O4 (LNMO) films as a cathode material were prepared by pulsed laser deposition on stainless steel substrates. X-ray diffraction and Field-emission Scanning Electron Microscope results show that the film deposited at 750°C exhibits good crystallinity with well-defined grains structure. Galvanostatic charge/discharge measurement results revealed that the reversible capacity maintains 116.8mAhg-1 after 100 cycles at 0.5C. It also exhibits excellent rate capability, as the rates increase to 5 and 10 C, about 95.4% and 92.3% of its initial capacity at 0.2C can be retained. In additional, thermal stability of the Al2O3 coated LNMO thin film cathodes were also explored. The high temperature cyclic performance of LNMO thin film electrode was significantly enhanced by the coating.
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Authors: Cui Yong Tang, Zhi Yu Xiao, Zhe Feng Zhuang, Wen Pan Dai, Su Ge Meng, Xiang Zhang, Xue Yong Chen
Abstract: Amorphous Fe79Ti16P5 alloy powders were synthesized from commercially available elemental powders by mechanical alloying. The microstructure, thermal stability and crystallization kinetic of as-milled powders were analyzed by XRD, SEM and DSC. Moreover, bulk ultrafine-grained materials were fabricated through spark plasma sintering of the amorphous powders. Results show that the amorphous powders exists two exothermal peaks during crystallization process. The effective activation energies for crystallization are obtained 109.14 kJ/mol and 205.97 kJ/mol for Ep1 and Ep2, respectively, by using the Kissinger method. The mechanical properties of the bulk materials are remarkably improved with the increase in the sintering temperatures. The ultimate compressive strength increases from 1282 MPa to 2015 MPa, but absence of ductility.
1259
Authors: Jia Wei Lu, Qun Zhi Zhu, Hong Yang Zhao, Xue Mei Qi
Abstract: Ten kinds of binary carbonate salts with different ratio were respectively prepared by two kinds of preparation processes and the research on thermo-physical properties, thermal stability and component analysis was worked respectively by Differential Scanning Calorimetry instrument and XRD analytical instrument. The results showed: There was little difference on melting point and decomposition point between the samples prepared by two kinds of methods and well matched with that of reference phase diagram; For the preparation of mixed carbonate, static melting method was superior to the simple mechanical grinding method through TG and DSC curves of multiple cycles; There was no new material produced in both two kinds of preparation processes from the XRD composition analysis.
941
Authors: Shuang Liang, Wang Yan, Ke Huang, Neng Luo, Shao Jun Wang
Abstract: Relative humidity in hot-humid and cold-humid area in summer is high, the sun radiation intensity is low, and the existing building thermal stability condition basic research data is absence . Select the region typical residential building, the sun radiation, relative humidity, air temperature and surface temperature were measured and recorded; Test analysis shows that typical residential house in summer in the climate characteristics the typical average indoor temperature fluctuation in the cycle is 4.3 °C,fluctuations of temperature to a larger extent, and was obviously affected by such factors as orientations and envelope constructional detail.
1193
Authors: Fei Yang, Xiao Yi Geng, Li Juan Zhang, Gang Ma, Ji Jun Xiao
Abstract: The polyimide foam (PIF) was prepared by the foaming of precursor derived from dimethyl ester of 3,3′,4,4′-biphenyltetracarboxylic dianhydride (BPDA) and 4,4′-diaminodiphenyl methane (MDA). The structure and properties of polymers were investigated by FTIR, 1H NMR, TG, DSC, SEM and mechanical testing. The findings show the PIF developed is of glass transition temperature of about 309°C, weight loss 5wt% at 517°C, density of 0.0018 g/cm3, cell structure of about 150μm, open-cell of 20%, thermal conductivity of 0.0277W/cm·K suitable for thermal insulation foam.
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Authors: Sen Zhou, Xu Jian Li, Yong Juan Shi, Chun Jie Yan
Abstract: The monodisperse functional Polystyrene/Silica (PS/silica) microsphere has been successfully prepared via suspension polymerization followed by the modified silica composite phenylethylene method. The FTIR, SEM, EDS and BEI were used to characterize the structure and composition of monodisperse functional PS/Silica microspheres. The results indicated that the dosage of silica modifier affect the compatibility of the modified silica and phenyl ethylene. The several modified silica would synergistically impact on the morphology and performance of products corresponding to distinguish formation mechanisms. The thermal stability and compressive strength performance had been improved compared with polystyrene (PS).The weight loss of PS/Silica microspheres were less than polystyrene (PS) which weightlessness ratio is 96.92 wt %. The compressive strength of PS/Silica microspheres was almost two times as many as pure PS microspheres. The formation mechanism of monodisperse functional PS/Silica microsphere was developed ahead according to the results of FTIR, SEM, EDS and BEI under various polymerization conditions.
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