Authors: Felipe M. Carvalho, Ronaldo M. Lasmar, Livia L.O. Goulart, Marcelo S. Siqueira, Ana Paola V. Braga
Abstract: The global production of niobium-microalloyed steels is now a well-established industrial practice. Initially driven by experimental insights into niobium's ability to refine steel microstructures during thermomechanical processing, this technology has become especially prevalent in low-alloy steels. An important aspect of niobium's production is its natural association with tantalum, which often leads to the co-extraction of both elements. This paper investigates the impact of tantalum traces, present as a contaminant in FeNb, on the microstructure and mechanical properties of niobium-microalloyed steels. The study reveals that tantalum's presence leads to further refinement of austenitic grains without negatively affecting the alloys' yield strength. Additionally, this tantalum contamination enhances the steel samples' toughness. By exploring these subtle effects, this study provides new insights into tantalum's influence on microalloyed steels, particularly regarding microstructural refinement and mechanical performance in two specific Nb-microalloyed steel compositions.
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Authors: Kevin Mark Banks, Dannis Rorisang Nkarapa Maubane
Abstract: Austenite restoration during thermomechanical (TM) rolling of typical vanadium-microalloyed structural steels was studied to optimize strength in the as-rolled and air-cooled condition. Multi-pass plate rolling simulations were performed on V-N microalloyed and CMn steels to compare recrystallisation behaviour in various temperature regions. Included were a conventional schedule ending at high temperature and two TM schedules with mill exit temperatures in the intermediate and low austenite regions. Increasing delay periods after roughing enhance the suppression of recrystallisation after the start of finishing thereby increasing both nucleation site density and nucleation rate for ferrite formation and refinement in grain size. Good agreement was found between microstructures after industrial TM rolling and those obtained from laboratory simulations. Although precipitation of vanadium carbonitrides is an effective strengthening mechanism, appreciable gains in yield strength due to grain refinement can be achieved by rolling in the lower austenite region. Low nitrogen contents in V steels produce coarser final ferrite grain sizes and lower strengths probably due to a larger precipitate size. V-N steels display similar flow behaviour to CMn grades down to approximately 825°C at low to intermediate strain rates but may experience alternate regions of work hardening and dynamic softening at lower temperatures in austenite.
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Authors: Kevin Mark Banks, Dannis Rorisang Nkarapa Maubane, Michelle Coleman
Abstract: Thermomechanical (TM) rolling schedules have been developed using mathematical modelling, physical simulation and industrial trials to produce C-Mn steel plate with yield strengths of 400MPa and good impact toughness without the need of expensive micro-alloying additions or accelerated cooling. The process relies on careful selection of delay times to accumulate sufficient retained strain during austenite conditioning for enhanced nucleation of ferrite. An integrated heat transfer-austenite processing model was used to predict the final microstructure and mechanical properties. The extent of strain accumulation and progress of recrystallisation during rolling were confirmed by laboratory simulation. Based on these results, carefully controlled industrial TM rolling trials were performed on C-Mn steels. Adequate grain refinement and properties are achieved through suppression of recrystallisation and strain accumulation in the low austenite temperature region after a sufficient delay period prior to finishing.
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Authors: Mahesh Chandra Somani, Jaakko I. Hannula, Antti Kaijalainen, Devesh K. Misra, David A. Porter
Abstract: Recent interests in developing novel super-high strength steels have led to extensive research efforts in direct quenching with or without tempering (DQ, DQT) or combined with partitioning (DQP). Both strip and plate products have been targeted for different applications. For boron-microalloyed DQ/DQT steels, the ASTM A255 approach for predicting the hardenability was considered inapplicable. Fresh attempts were made to develop new hardenability models through non-linear regression analysis by dynamically varying both the boron factor and multiplying factors of most elements in the alloy factor. Based on the recent concept of quenching and partitioning (Q&P), a novel processing route comprising thermomechanical rolling followed by direct quenching and partitioning (TMR-DQP) has been established for the development of ultra-high strength structural steels with yield strengths ≈1100 MPa combined with good uniform and total elongations and impact toughness. Examples of recent advances made in DQ processing and associated challenges, such as those related to the bendability of low carbon martensitic-bainitic steels and influence of boron on the toughness of Nb-bearing martensitic steels are presented.
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