Papers by Keyword: Time-Temperature-Stress Superposition Principle

Abstract: A new accelerated characterization model for creep performances was briefly introduced first, which considers both the effects of temperature and stress level, named time-temperature- stress superposition principle (TTSSP). TTSSP assumes that the influence of stress level on the intrinsic time is similar to that of temperature for the creep behavior, as well as damage and physical aging. The creep curves at different state can be shifted into a master curve at reference state using TTSSP. Then the long-term creep behavior of viscoelastic materials at lower temperature and/or stress level can be predicted from the short-term ones. Finally, TTSSP was used to investigate the nonlinear creep behavior of high-density polyethylene (HDPE). It was shown that the long-term creep behavior of HDPE can be predicted successfully.

Abstract: Based on the observations that high temperature accelerates creep rate of polymer while physical ageing plays a reverse role, and that there is an analogy between the influences of stress and temperature on the intrinsic times of polymers, the time-ageing time superposition principle (TASP) and the time-temperature-stress superposition principle (TTSSP) are used to evaluate the long-term creep behavior of poly(methyl methacrylate) (PMMA). PMMA specimens were aged for 2 to 120 hours at identical temperature, their short-term creep strains with 2-hour test duration were measured under various stress levels ranging from 14 to 30 MPa at room temperature, and modeled by means of time-ageing time equivalence and time-stress equivalence. The results show that the creep rate increases with stress, but decreases with ageing time. The ageing time shift factors vary with the stresses at which the shifts are applied. The ageing shift rate is independent on imposed stress in linear viscoelastic region, while it decreases with increasing stress when the material behaves in a nonlinear viscoelastic manner. The master creep compliance curve up to about 1-month at reference ageing time 120 hours and stress 18 MPa, which is nearly 2.5 decades longer than the test duration, is constructed by shifting the creep curves horizontally along the logarithmic time axis. The result illustrates that TTSSP, combined with TASP, provides an effective accelerated test technique for long-term mechanical behaviors of polymers.

Abstract: The mechanical behaviors were investigated by nonlinear creep tests of poly(methyl methacrylate) under different temperatures. The test duration was 4000 seconds. The corresponding temperature shift factors, stress shift factors and temperature-stress shift factors were obtained according to time-temperature superposition principle, the time-stress superposition principle and the time-temperature-stress superposition principle (TTSSP). The master creep compliance curve up to about 1-month at a reference temperature 22 degrees centigrade and a reference stress 14 MPa was constructed, and the effect of stress-induced damage evolution on the long-term creep behavior of polymeric material was accounted. It was shown that TTSSP provides an effective accelerated test technique in the laboratory, the results obtained from a short-term creep test of poly(methyl methacrylate) specimen at high temperature and stress level can be used to construct the master creep compliance curve for prediction of the long-term mechanical properties at relatively lower temperature and stress level, and the master creep compliance curve with damage considered can be applied to accurately characterize the long-term creep behavior of nonlinear viscoelastic polymer.