Authors: Supitcha Rungrodnimitchai, Sirinapa Mayod, Suphatra Hiranphinyophat, Ditpon Kotatha, Chittra Dokbua
Abstract: In this study, oxidized cellulose nanofiber was prepared from squeeze dried Nata de Coco sheet by the oxidation system of HNO3/H3PO4-NaNO2 at 30 °C for 24 hours. The ratio between HNO3 and H3PO4 was 1:3 v/v and the concentration of NaNO2 was 1.4% w/v. The carboxyl content and %yield of oxidized cellulose nanofiber from Nata de Coco (Nata-OC) was 28.6% and 68.4%, respectively. Then the Nata-OC was treated by several types of bases. Sodium hydroxide (NaOH) or triethanolamine (TEA) treated Nata-OC showed superior in gelation property to the original Nata-OC. The powder of base-treated Nata-OC gave stable Nata-OC aqueous dispersion, which might be applicable for spray-typed materials. The test papers obtained from 10% of base-treated Nata-OC dispersion showed good blood agglutinating property as same as dry sheet of pure Nata-OC. Moreover, the dispersion of base-treated Nata-OC could be coated on the surface of gauze without any additive.
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Authors: Wei Feng Zhang, Jian Shao
Abstract: A small hollow-fiber membrane contactor system was used to test the absorption and desorption CO2 using mixed absorption solution of SG/PG and TEA. The results showed that absorption effect of SG was better than PG under low concentrations, but their desorption was the opposite. With the increase of concentration, the absorption effect of SG tended to weak, while the desorption was enhanced. And, PG was contrary. The absorption effect of mixed solution(SG+TEA, PG+TEA) was excellent when adding small amount of TEA. And, the absorption effect of TEA-SG mixed solution was amazing under the low concentration of SG. With the concentration of mixed solution increased, the auxo-action of TEA weakened. Instead, TEA played a active effect on promoting the absorption of TEA+PG mixture with the increasing of concentration. The hybrid experimental results shown that 3mol/L PG+0.1 mol/L TEA mixture absorption solution was best in absorption experiments, and 1mol/L PG+0.2 mol/L TEA mixture absorption solution was best in desorption experiments.
1546
Abstract: Novel functionalised absorbents have been synthesized by immobilization of triethanolamine on synthetic mesoporous silica for CO2 capture. Mesoporous silica material with a uniform pore size of 20-50nm and a surface area of 200~300 m2/g was used as loader for capturing agents. The capture of carbon dioxide from simulated flue gas streams has been achieved by using triethanolamine immobilized mesoporous silica. Preliminary attempts have also been made to determine the CO2 adsorption capacities of these newly developed materials. The results revealed that maximum adsorption capacities was 28.01mg/g for immobilized triethanolamine mesoporous silica at room temperature,and the rate of desorption is 99% at 90°C.Recycle of adsorption-desorption have many times,and the ability of capturing CO2 was stable. The results suggest that immobilized triethanolamine have a good affinity for the capture of carbon dioxide from simulated flue gas streams.The performance of these immobilized and triethanolamine-mesoporous silica solid sorbents decreased with regeneration.
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Authors: Ming Jer Jeng, Wen Kai Lei
Abstract: The electrodeposited CuInSe2 films were investigated in this paper. The deposition parameters of various solution concentrations, applied potential, pH value and complexing agent were examined to characterize film quality. The electrolyte solution was formed by mixing an appropriate proportion of copper sulfate, indium sulfate and selenium dioxide. Sodium citrate was used as complexing agent. Citric and sulfuric acids were used for adjusting electrolyte pH value. The experimental results revealed that the deposited and annealed CIS films have an atomic ratio of [Cu]:[In]:[Se] = 26.94:26.74:46.31. It is near to the stoichiometry of an atomic ratio ([Cu]:[In]:[Se] = 1:1:2). Unfortunately, this film has a poor adhesion problem. In order to overcome the adhesion problem, the triethanolamine and sodium dodecyl sulfate are used as complexing agents and wetting agents, respectively. A good adhesion was obtained. However, these additives result in a shortcoming of insufficient indium content in the formation film.
378
Authors: Xiu Ling Zhang, Xiao Ming Jia, Jian Xiao Lian
Abstract: The reactionary trend of the triethanolamine and cobalt in cemented carbide and the mechanism of cobalt leaching have been investigated by soaking experiments, friction experiments and electrochemical gaging experiments. The experimental results reveal that triethanolamine is prone to form coordination compound with cobalt ion .The amount of cobalt’s element leaching from cemented carbide is added up with the increase of time and triethanolamine concentration. So when using cemented carbide cutting tool, the water-based cutting fluid containing triethanolamine addictive should be avoided.
1203
Authors: Mohammad Ghorbani, Milad Roushanafshar
Abstract: Titania Nanopowders were successfully deposited on stainless steel sheet by means of electrophoretic deposition method from titania suspension in which isopropanol was employed as a solvent and Triethanolamine as a dispersant. The effect of TEA addition on the stability of nanopowders in suspensions was examined by sedimentation test; in addition, Malvern zeta sizer was employed for determination their particle size. Electrophoretic Deposition was done at different deposition conditions of voltage (5-20 volts) and time (5-60 sec) and the scanning electron microscopy (SEM) was used to investigate the effect of suspension composition and deposition parameters on the microstructure of coatings. Furthermore, the effect of deposition parameters on the consistencies of different coatings was analyzed by Scanning Probe Microscope (SPM).
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