Authors: Zhan Ling Zhang, Yong Ning Liu, Jie Wu Zhu, G. Yu
Abstract: Ultrahigh carbon steel containing 1.6 wt pct C was processed to create microduplex
structure consisting of fine-spheroidized carbides and fine ferrite grains. Elongation-to-failure tests
were conducted at strain rates from 10-4s-1 to 15×10-4s-1, and at temperatures from 600 °C to 850 °C.
The steel exhibited superplasticity at and above 700 °C when testing at a strain rate of 10-4s-1, and at
800 °C when testing at strain rates of 7×10-4s-1 and slower. The grains retained the equiaxed shape
and initial size during deformation; dynamic grain growth was not observed after superplastic
deformation, whereas carbide coarsening was observed. It is concluded that the fine ferrite grains or
austensite grains are stabilized by the grain boundary carbides, and grain-boundary sliding
controlled by grain boundary diffusion is the principal superplastic deformation mechanism at
temperatures in the range of 700-850 °C.
199
Authors: Hai Sheng Shi, Guang Min Luo, Jun Fei Fan, Yi Jian Lin, Jing Guo Zhang
Abstract: The effect of hot rolling parameters on graphitization of a spray formed
ultra high carbon steels(UHCSs) was described. The number of graphite stringers and
graphite area fractions increased with the increase of rolling reduction. Graphite
stringers nucleated at small pores and grew by carbon diffusion from adjacent
austenite during hot rolling. Alloy contents, pores and hot deformation atγ+Fe3C
phase range are the key factors for graphitization.The graphite stringers of UHCSs
have little effect on tensile strength, but reduce the ductility at room temperature.
4550
Authors: C.K. Syn, D.R. Lesuer, A. Goldberg, H.C. Tsai, Oleg D. Sherby
Abstract: The properties of ultrahigh carbon steels (UHCS) are strongly influenced by aluminum
additions. Hardness studies of quenched UHCS-Al alloys reveal that the temperature for the start of
transformation increases with increases in aluminum content. It is shown that this change is a
function of the atomic percent of solute and of the valence state when comparisons are made with
UHCSs containing silicon and tin as solutes. The thermal expansion of UHCSs with dilute
aluminum additions shows no discontinuity in the vicinity of the ferrite-austenite transformation
temperature. This is the result of a three phase region of ferrite, carbides and austenite. The slope of
the expansion curve is higher in the austenite range than in the ferrite range as a result of the
dissolution of carbon in austenite with temperature. Processing to achieve a fine grain size in
UHCS-Al alloys was principally by hot and warm working (HWW) followed by isothermal warm
working (IWW). The high temperature mechanical properties of a UHCS-10Al-1.5C material show
nearly Newtonian-viscous behavior at 900 to 10000C. Tensile elongations of 1200% without failure
were achieved in the 1.5%C material. The high oxidation corrosion resistance of the UHCS-10Al
materials is described.
4844
Authors: Manuel Carsí, A. Fernández-Vicente, Oleg D. Sherby, Félix Peñalba, Oscar Ruano
Abstract: Thermomechanical processing allows the attainment of spheroidized microstructures that
show improved mechanical properties. In this work, a thermomechanical processing route
consisting of two steps was developed for two ultrahigh carbon steels (UHCS) containing 1.3 and
1.5%C. This route develops structures of fine spheroidized cementite particles in a fine-grained
ferrite matrix. Spheroidized microstructures are formed by eutectoid carbide particles in the UHCS-
1.3C and by proeutectoid and eutectoid carbide particles in the UHCS-1.5C. In the latter steel, the
proeutectoid carbide particle size is larger than the eutectoid carbide particle size. The carbide size
distribution remains basically constant with austenitizing temperature for both steels. Plane-strain
fracture toughness of spheroidized UHCS-1.3C is higher than for UHCS-1.5C, about 80 vs 40 MPa
m1/2. These values do not vary significantly with austenitizing temperature which is attributed to
the constancy of the mean proeutectoid and eutectoid carbide size.
4826
Authors: Oscar Ruano, Toshi Oyama, Oleg D. Sherby
Abstract: Superplastic properties of fine-grained ultrahigh carbon steels (UHCS) have been
greatly improved through the addition of 3 wt% Si (UHCS-3Si) and through improved processing
conditions. This material showed an elongation to failure of 1300% under optimum superplastic
conditions. It is also superplastic at very high strain rates, i.e. 10-2 s-1, in the temperature range
between 800 and 825°C. An analysis of the effect of silicon additions on the UHCS and the
influence of the introduction of temperatures regions in the phase diagram on the superplastic
properties is made.
4801
Authors: M.A. Martinez, J. Abenojar, J.M. Mota, R. Calabrés
Abstract: The objective of the present work is to study the manufacturing process of steels
with high carbon content (1.5–2.1wt%) obtained by powder metallurgy. The reference
material was the Damascus steel, which was employed to manufacture swords named after it
and has been widely known due to its very good mechanical properties. The main reasons of
the success of this product are: the high carbon content of the initial steel and the
thermomechanical treatment (forge and quenching) that ancient iron forgers kept secretly
during centuries. Different carbon contents (2 to3 wt%) were added to the same Fe powder
matrix (ASC 300), and compacted and sintered steels are heat laminated (750°C) with a
reduction of 20%. For 2% carbon content, the result is a steel with yield strength of 450 MPa,
Young’s Modulus of 14.3 GPa and hardness of 109 HV(30).
328
Authors: Wei Ping Lin, Ya Jun Fan, Zhan Ling Zhang, Jie Wu Zhu, Yong Ning Liu
Abstract: A ultrahigh carbon steels (UHCS) containing 1.6 wt pct carbon was studied. Through
spheroidizing process by divorced-eutectoid transformation (DET), the forged microstructure was
spheroidized and the microstructure was fine carbide particles distributed in ferrite matrix.
Second-time heat treatment included two kinds of technologies: normalizing and quenching +
tempering. Finally, the UHCS obtained ideal mechanical properties. The yield strength and tensile
strength of the UHCS were higher than that of 40CrNiMo, moreover plasticity of the UHCS was
equal to that of 40CrNiMo. So the UHCS was an excellent structural material.
907
Authors: Xiao Jun Li, Jing Guo Zhang, Hai Sheng Shi, Jian Sheng Wu
2841
Authors: Jing Guo Zhang, Guang Min Luo, Xiao Jun Li, Jun Wang, Biao Yan, Yi Jian Lin, Hai Sheng Shi, Hao Zhang
Abstract: The recent investigations on spray formed ultrahigh-carbon steels (UHCSs) are reviewed. A satisfactory combination of strength and ductility in spray formed UHCSs can be obtained by hot rolling and annealing. The composition and hot rolling have a marked effect on the formation of graphite in UHCSs. The possibility of achieving high strain rate superplasticity in the spray formed UHCS was first revealed by very recent investigations in Shanghai Baosteel Research Institute. The
UHCS processed by a combination of spray forming and hot rolling exhibited high strain rate superplasticity.
2779
Authors: C.K. Syn, Donald R. Lesueur, Oleg D. Sherby, Eric M. Taleff
853