Authors: Toi Aoki, Noboru Nakayama, Masaomi Horita, Hiroaki Fukui
Abstract: Pressure-sensitive conductive material is used for various pressure sensors consists of a polymer nanocomposite with carbon nanotubes (VGCF). And the resistance in it were changed by adding applied load. Recently, carbon nanotubes (VGCF) has drawn attention as a function filler that imparts various functions to a resin, including electrical properties. In polycarbonate (PC) composite with VGCF, the resistance decreases with increase in applied load. And increase of the addition amount of VGCF was enhanced the mechanical properties and electronic properties. In addition, this conclusion suggested that strain of PC/VGCF caused reducing the resistance. Therefore, changing matrix is predictably effective on electrical properties in pressure-conductive materials. In the present study, we used various matrix had different elastic modulus. The addition amount of VGCF was 12.5% volume rate. We made silicone/VGCF and polyethylene (PE)/VGCF and polycarbonate (PC)/VGCF by twin screw extruder and injection moldings. To clarify the influence of elastic modulus of matrix on conductivity of VGCF dispersed plastic matrix composites. The experimental results showed that conductive property of pressure-sensitive conductive materials is related to elastic modulus of them.
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Authors: Gen Sasaki, Zhe Feng Xu, Yong Bum Choi, Kenjiro Sugio, Kazuhiro Mastugi
Abstract: As vapor grown carbon fiber (VGCF) possesses the good mechanical properties, high thermal conductivity, high electrical conductivity and low thermal expansion, VGCF/ Al composites are expected to be suitable materials for a high performance radiator. In this study, VGCF were dipped and treated with ultrasonic vibration in some kinds of solution at first. Then, the mixed powders including three kind of average particle size of Al (1, 3 and 30µm) was milled by wet process with three kinds of solution, which are acetone, ethanol and butanol. Ethanol is most suitable for mixing solution because of homogeneous distribution of VGCF and Al powders. The mixed powders were spark-sintered in order to obtain dense VGCF/Al composites. The densification mechanism of VGCF/Al composites was divided into the plastic deformation (2nd stage) and creep deformation (3rd stage) after the 1st stage of rectangular wave pulse discharge. The densification rate of VGCF/Al composite powder depended on Al powder for matrix, but independent on VGCF. VGCF are dispersed uniformly in the VGCF/1 µm Al composite. But the aggregations of VGCF exhibited a preferential orientation in VGCF/30 µm Al composite, which results from the deformation of Al powders under the uniaxial pressure during the hot pressing in sintering process.
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Authors: Dan Na Qian, An Chang Xu, Li Min Bao, Masayuki Takatera
Abstract: The solid particle erosion behavior of the body materials used in high-speed moving equipments has attracted widely attention from researchers. In order to enhance the erosion resistance of existing FRP materials and to develop new FRP materials with high strength and excellent erosion resistance, we attempted to use VGCF (vapor-grown carbon fiber) with high strength and high modulus as filler for reinforcing UP resin matrix. In this study, VGCFs were treated by UV ozone treatment for improving the interface adhesion, and the effects of the filler weight content, impact angle and impact velocity upon the erosion wear behavior of UP resin composite materials have been carried out. The mechanical properties of composites materials reinforced by VGCF were also evaluated. The results indicate that it is feasible to improve the erosion resistance and flexural properties of UP resin by VGCF filler simultaneously.
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Authors: Gen Sasaki, Fumiaki Kondo, Kazuhiro Matsugi, Osamu Yanagisawa
Abstract: Vapor grown carbon fiber (VGCF) was sleaved in acetone with ultrasonic vibration. Then
pure aluminum powders with 3 μm in average diameter was poured into VGCF containing acetone
and mixed with ultrasonic vibration. The composites were fabricated by electro spark sintering. The
strength, rigidity, electrical conductivity and microstructure of the composites was investigated.
VGCF was distributed uniformly and no pores was observed in composite. As increasing the
volume fraction of VGCF in composites, the strength of composites increased gradually but the
elongation decreased. The electrical resistivity of the composites increased as increasing VGCF
content, constantly. The theoretical resistivity of composites without residual stress is lower than
that of experimental results. It seems that is caused by the high dislocation density and strain
introduced by big difference of thermal expansion between VGCF and pure aluminum.
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Authors: Katsuhiko Sasakir, Terumitsu Imanishi, Kazuaki Katagiri, Atushi Kakitsuji, Toyohiro Satoh, Akiyuki Shimizu, Nobuhito Nakama
Abstract: In this paper, carbon nanotube (CNT) containing aluminum composite materials, which
have good thermal conductivity, are made by the plasma activated sintering. CNT and vapor-grown
carbon fiver (VGCF) as a super multi-wall CNT are used for the composite materials. To clarify the
deformation and thermal characteristic of the composite materials, Young’s modulus and thermal
conductivity are measured. Finally, the micromechanical discussion is also conducted using
Mori-Tanaka model.
587
Authors: Joon Hyung Byun, Kyeong Sik Min, Yeun Ho Yu, Moon Kwang Um, Sang Kwan Lee
Abstract: This study describes a method of good dispersion and alignment of VGCFs, and examines
the effect of nanofiber content on the mechanical properties of nanocomposites. The dispersion of
nanofibers was carried out by solution blending, mechanical mixing, and sonication. Levels of 4% –
31% volume content of VGCFs were mixed with polypropylene (PP) powder, and then were
melt-mixed using a twin-screw extruder. For the further alignment of fibers, extruded rods were
stacked in the mold cavity for the compression molding. In the case of 31% volume content, tensile
modulus and strength improved by 100% and 40%, and the flexural modulus and strength increased
by 120% and 25%, respectively. The shear modulus showed 65% increase, but the strength dropped
sharply by 40%. In the transverse direction, the tensile, flexural, and shear strength decreased as more
fibers were added. The matrix modification by maleic anhydride (MAPP) increased the tensile and
flexural properties of VGCF/PP by 20% - 30% in the longitudinal direction, and 40% - 250% increase
in the transverse direction. The fiber surface treatment by plasma improved tensile and flexural
properties of untreated VGCF/PP (18 % vol) composites by 10% - 30% in the longitudinal direction,
but strength in the transverse direction decreased by 30% - 40%.
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