Papers by Keyword: Vanadium Carbide

Abstract: This paper presents a study on the synthesis of Niobium Carbide (NbC) and Vanadium Carbide (VC) in Copper (Cu) matrix by mechanical alloying (MA) technique. The elemental powders of Cu, Niobium (Nb), Vanadium (V) and synthetic graphite powder were mechanically alloyed for 30 hours at 400 rpm in a planetary ball mill Fritcsh “Pulverisette 6” according to the stoichiometric ratio of Cu-(10-x) vol%NbC-(0+x) vol%VC (x=1,3,5,7,9). The milling was performed under Argon atmosphere. The as-milled powder were compacted at 400 MPa and sintered using a microwave sintering furnace at 900°C with 1 hour soaking time. The phase identification was performed by using the X-ray Diffraction (XRD) analysis on the as-milled powders and sintered pellets. From the result, the NbC and VC phases were successfully formed after milling, and were precipitated after sintering. The average crystallite size and lattice strain of Cu, before and after sintering were 42.302 nm, 0.013%, and 71.294 nm, 0.004%, respectively.

Abstract: The electron beam cladding of vanadium and graphite powder mixture with additions of the flux agents on thick steel workpieces was implemented using the “ELV-6” electron accelerator. Structural and tribological investigations of the hardened surface were carried out. It was shown that cladding of vanadium-carbon powder mixtures by high-power electron beam injected to the atmosphere led to formation of high quality coatings. The highest microhardness level of cladded layer reached 12 GPa. Thickness of the surface layer was in the range 2.5-3.4 mm. Concentration of hard vanadium carbide particles increased with decrease of layer thickness which resulted in growing the wear resistance level of modified material.

Abstract: Vanadium carbide is less dense, harder and tougher than tungsten carbide, and nickel is more corrosion resistant that cobalt. Replacing the binder with Ni should improve the corrosion resistance. Since there are eutectics with a wide range of compositions in the C-Ni-V system, this system has potential for wear resistant alloys with ~VC as the discrete hard phase and the nickel solid solution as the binder. The aim of this work was to ascertain if eutectic microstructures with vanadium carbides could be beneficial to wear resistance. Phase studies confirmed the wide range of the eutectic alloys, with VC + (Ni), VC + σ′, VC + (V) and graphite + (Ni) and different morphologies. Preliminary wear tests showed results comparable to WC-Co alloys.

Abstract: Diffusion couples of the type WC-Co/VC-Co were employed to observe the diffusion behaviour of the grain-growth inhibitor (GGI) VC within nanoand ultrafine-grained WC-10wt.% Co samples. Since diffusion of the GGI during heating occurs already in the solid-state regime, interrupted sintering experiments were performed up to the liquid phase formation temperatures. By the use of light-optical and scanning electron microscopy the impact of GGI concentration on the microstructure as a function of depth from the interface was investigated. Electron Probe Microanalysis (EPMA) was used in order to quantify the amount of vanadium diffused into WC-Co as a function of distance. In first approximation, an activation energy of 3.45 eV (332,6 kJ/mol) for vanadium transport was determined.

Abstract: This paper analyzed thermodynamic principle of preparation VC,VN and V(C,N) with V₂O₅ and C by carbon-heat reduction. The results show that synthesizing process includes phase change and the vanadium oxide is reduced gradually. And because of the reaction kinetics, there are no obvious boundaries between each reaction. There are two principles for V₂O₅ reducing by carbon thermal method. One reaction depends mainly on CO/CO₂ gas-solid transmitted and another reaction depends mainly on the solid-solid reaction between carbon and vanadium oxide. But no matter what kind of mixing method, two kinds of reaction mechanism are also present in different degree. The reacting principle which is primary is depended on original mixed condition between V₂O₅ and C. It is propitious to reducing process by increasing temperature. The preparation of VC should be done at the condition with CO or vacuum.

Abstract: The purpose of this study is to investigate the fatigue characteristic and fatigue fracture mechanism of the high V-Cr-Ni spheroidal carbide cast iron (SCI-VCrNi) with spheroidal vanadium carbide (VC) dispersed within austenitic stainless matrix microstructure. The SCI-VCrNi that has high hardness was developed by 10mass%V adding to 18-8 stainless steel with spheroidal VC is distributed in the matrix. Firstly from the plane bending, the fatigue limit σw has been found to the 358MPa of SCI-VCrNi. Secondly, fracture surface observations were performed to clarify the fatigue mechanism of SCI-VCrNi. The fracture surface of SCI-VCrNi was so rough that the beach mark could not be observed. So, SEM was employed to observe, the fatigue fracture surface which showed a particular fatigue pattern. Also, many fracture cracks of VC were observed. In addition, the secondary cracks are shown at the interface between VC and the matrix. It can be suggested that the bondability between VC and the matrix is strong, and therefore, the propagation of cracks was delayed by the breakage of VC.

Abstract: In the thermal spraying process, spray material is heated, melted, and accelerated by a high temperature flame. Thermal spraying can produce thick materials that rapidly solidify, because the alloy droplets accumulate successively on the substrate and solidify at a cooling rate in the range of 105-108Ks-1. Depending on the cooling conditions of the substrate and on the alloy composition, deposits are produced with metastable phases or extremely fine crystalline phases. Thermal spraying is an attractive method for the production of composite deposits with fine particles formed in-situ. In particular, iron based alloy with vanadium carbide, is useful in metal molds and also in pump parts due to its high wear resistance and high corrosion resistance. In the present work, low-pressure plasma spraying of Fe-C-V/Ni-Mg and Fe-C-V-Cr-Ni/Ni-Mg blend powders were iron based composite deposits with finely dispersed vanadium carbide particles. The as-sprayed deposit produced from Fe-C-V/Ni-Mg blend powder is composed of αFe and V8C7. The as-sprayed deposit produced from Fe-C-V-Cr-Ni/Ni-Mg blend powder is made up of γFe, αFe, V8C7 and Cr7C3. The fine precipitates of approximately 0.3μm in the as-sprayed deposit are carbide. With increasing the heat-treatment temperature up to 1273K, the carbide particles coarsen. The hardness of as-sprayed deposit produced from the Fe-C-V-Cr-Ni/Ni-Mg, which has many fine carbide precipitates, is the hardest of the deposits.

Abstract: This work presents the investigation results of laser remelting and alloying especially the laser parameters and its influence on the structure and properties of the surface of the 32CrMoV12-28 hot work steel, using the high power diode laser (HPDL). As a result structure changes in form of fragmentation were determined. The reason of this work was to determine the optimal laser treatment parameters, particularly the laser power to achieve good layer hardness for protection of this hot work tool steel from losing their work stability and to make the tool surface more resistant to action in hard conditions. For alloying the tantalum carbide, tungsten carbide and vanadium carbide powders were used. For investigations hardness measurements of the different remelting areas were performed. The remelted layers which were formed in the surface of investigated hot work steel were examined metallographically and analyzed using light and electron microscope. Three phases of carbides, TaC, VC and WC, were observed.

Abstract: High performance commercial micro alloyed steels contain elements such as vanadium, which leads to a fine dispersion of vanadium carbide precipitates. The precipitation state, in terms of volume fraction and size distribution, plays a significant role in final mechanical properties of the material. Different austenitisation heat treatments were performed on a model ternary alloy FeCV. Precipitation states were characterised combining different experimental techniques. TEM was used to identify the chemical composition of observed precipitates. ICP mass spectroscopy was performed to measure the volume fraction of precipitates. The size distribution was studied by SEM. Results are characteristic of a coarsening regime.