Synthesis, Characterization and Efficiency of N, C-TiO2 as an Active Visible Light Photocatalyst


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Elemental doping of titanium dioxide with nitrogen and carbon were investigated in this study to get the modified photocatalyst working under visible light. Doped and codoped photocatalyst samples were synthesized by solgel method using titanium isopropoxide, ammonium nitrate and acetylacetone as precursors with the dopant concentration and calcination temperature fixed at 0.75% and 600°C respectively. Synthesized photocatalysts were characterized by XRD, FTIR and FESEM to check the existence of anatase phase, presence of dopants and formation of fine particles respectively. The effectiveness of the synthesized photocatalysts was measured by performing a standard batch photodegradation test with methylene blue as a model pollutant under ordinary visible light. The photocatalytic degradation efficiencies were found to be affected by the presence of dopant elements. The codoped photoctalyst (N-C-TiO2) exhibited the highest photocatalytic activity as it resulted in 91.3% degradation of methylene blue over 180 minutes of irradiation time.



Edited by:

Azmi Mohamed Yusof




J. Krishnan et al., "Synthesis, Characterization and Efficiency of N, C-TiO2 as an Active Visible Light Photocatalyst", Applied Mechanics and Materials, Vol. 661, pp. 63-67, 2014

Online since:

October 2014




* - Corresponding Author

[1] H. Yu, X. Zheng, Z. Yin, F. Tag, B. Fang, and K. Hou: submitted to Chinese Journal of Chemical Engineering (2007).

[2] Arman Sikirman, Jagannathan Krishan, Faraziehan Senusi and Junaidah Jai: submitted to Advance Material Research (2014).


[3] Q. Ling, J. Sun, and Q. Zhou: submitted to Applied Surface Science (2008).

[4] S. Rehman, R. Ullah, A. M. Butt, and N. D. Gohar: submitted to Journal of Hazardous Material (2009).

[5] J. Yang, H. Bai, X. Tan, and J. Lian: submitted to Applied Surface Science (2006).

[6] X. S. Shen, J. Guo, Z. C. Liu, and S. M. Xie: submitted to Applied Surface Science (2008).

[7] T. K. Tseng, Y. S. Lin, Y. J. Chen, and H. Chu: submitted to Molecular Science (2010).

[8] T. C. Jagadale, S. P. Takale, R. S. Sonawane, H. M. Joshi, S. I. Patil, B. B. Kale: submitted to Journal of Physical Chemistry (2008).

[9] W. Jo and J. Kim: submitted to Journal of Hazardous Material (2009).

[10] G. Veréb, Z. Ambrus, Z. Pap, Á. Kmetykó, A. Dombi, V. Danciu: submitted to Applied Catalyst A: (2012).

[11] X. Wu, S. Yin, Q. Dong, C. Guo, H. Li, T. Kimura: submitted to Applied Catalyst B: Environment (2013).

[12] Y. Niu, M. Xing, J. Zhang, and B. Tian: submitted to Catalyst Today (2012).

[13] J. Xu, Y. Ao, M. Chen, and D. Fu: submitted to Journal of Alloys and Compounds (2009).

[14] Y. Wu, M. Xing, B. Tian, J. Zhang, and F. Chen: submitted to Chemical Engineering Journal (2010).

[15] A. P. Mangrulkar, S. P. Kamble, M. M. Joshi, J. S. Meshram, N. K. Labhsetwar, and S. S. Rayalu: submitted to Journal of Photoenergy (2012).

[16] G. Tian, Y. Chen, K. Pan, D. Wang, W. Zhou, Z. Ren: submitted to Applied Surface Science (2010).