Removal of Phosphate from Wastewater Using Carbonized Filter Cake

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The aim of this work was to study the potential of the agricultural waste byproduct as a low-cost adsorbent for removal of phosphate ion (PO43-) from synthetic wastewater. The simple preparation of carbonized filter cake (CFC) was performed at 550°C. CFC was also characterized using FTIR, X-ray fluorescence analysis. The adsorptive parameters of batch experiment, such as pH of solution, dosage and contact time were systematically studied in order to the optimization condition. The optimum conditions of pH, contact time and adsorbent dose were to be 6, 60 min, and 2 g/L, respectively. The Langmuir and Freundlich isotherms were used to calculate the adsorption parameters that was able to describe the equilibrium isotherm and adsorptive mechanism. The maximum monolayer adsorption capacity of CFC was estimated as 20.32 mg/g. The optimized condition was applied for phosphate removal from synthetic wastewater. The achieved phosphate removal efficiency from synthetic wastewater sample was to be 92.4%. Filter cake is a low-cost byproduct of sugar cane but it can also highly effective remove phosphate ion from aqueous solution. The modification of filter cake surface via chemical reaction as a new adsorbent in order to increase surface sites and high affinity with phosphate ion will also be further studied.

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Edited by:

Dr. Noppakun Sanpo, Dr. Jirasak Tharajak and Dr. Paisan Kanthang

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125-130

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W. Chansuvarn, "Removal of Phosphate from Wastewater Using Carbonized Filter Cake", Applied Mechanics and Materials, Vol. 879, pp. 125-130, 2018

Online since:

March 2018

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$38.00

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[1] M. Kumar, A. Puri, A review of permissible limits of drinking water, Indian J. Occup. Environ. Med., 16 (2012) 40-44.

DOI: https://doi.org/10.4103/0019-5278.99696

[2] W. Huang, Y. Zhang, D. Li, Adsorptive removal of phosphate from water using mesoporous materials: A review, J. Environ. Manag. 193 (2017) 470-482.

[3] S. Gisi, G. Lofrano, M. Grassi, M. Notarnicola, Characteristics and adsorption capacities of low-cost sorbents for wastewater treatment: A review, Sustain. Mater. Technol. 9 (2016) 10-40.

DOI: https://doi.org/10.1016/j.susmat.2016.06.002

[4] Y. Wang, D. Sun, Phosphate removal from aqueous solutions on fly ash with medium calcium content, Korean J. Chem. Eng. 32 (2015) 1323-1326.

DOI: https://doi.org/10.1007/s11814-014-0342-6

[5] L. Zhang, W. Wu, J. Liu, Q. Zhou, J. Luo, J. Zhang, X. Wang, Removal of phosphate from water using raw and activated laterite: batch and column studies, Desalin. Water Treat. 52 (2014) 778-783.

DOI: https://doi.org/10.1080/19443994.2013.826786

[6] Y. Yang, Y.Q. Zhao, A.O. Babatunde, L. Wang, Y.X. Ren, Y. Han, Characteristics and mechanisms of phosphate adsorption on dewatered alum sludge. Sep. Purif. Technol. 51 (2006) 193-200.

DOI: https://doi.org/10.1016/j.seppur.2006.01.013

[7] T. He, Z. Li, Y. Gong, The preparation and phosphate adsorption experiments of new modified bamboo powder, Adv. Mater. Research. 1081 (2015) 20-24.

DOI: https://doi.org/10.4028/www.scientific.net/amr.1081.20

[8] Y. Yan, X. Sun, F. Ma, J. Li, J. Shen, W. Han, X. Liu, L. Wang. Removal of phosphate from wastewater using alkaline residue, J. Environ. Sci. 26 (2014) 970-980.

[9] L. Lai, Q. Xie, L. Chi, W. Gu, D. Wu, Adsorption of phosphate from water by easily separable Fe3O4@SiO2 core/shell magnetic nanoparticles functionalized with hydrous lanthanum oxide, J. Colloid Interf. Sci. 465 (2016) 76-82.

DOI: https://doi.org/10.1016/j.jcis.2015.11.043

[10] D.H. Santos, M.A. Silva, C.S. Tiritan, C.A.C. Crusciol, The effect of filter cakes enriched with soluble phosphorus used as a fertilizer on the sugarcane ratoons, Acta Sci. Agron. 36 (2014) 365-372.

DOI: https://doi.org/10.4025/actasciagron.v36i3.17791

[11] E.A. Nagul, I.D. McKelvie, P.J. Worsfold, S.D. Kolev, The molybdenum blue reaction for the determination of orthophosphate revisited: Opening the black box, Anal. Chim. Acta. 890 (2015) 60-82.

DOI: https://doi.org/10.1016/j.aca.2015.07.030

[12] C.A. Rezende, M.A. de Lima, P. Mazierode, E.R. Azevedo, W, Garcia, I. Polikarpov, Chemical and morphological characterization of sugarcane bagasse submitted to a delignification process for enhanced enzymatic digestibility. Biotechnol. Biofuels. 4 (2011).

DOI: https://doi.org/10.1186/1754-6834-4-54

[13] S. Norsuraya , H. Fazlena , R. Norhasyimi, Sugarcane bagasse as a renewable source of silica to synthesize santa barbara amorphous-15 (SBA-15), Procedia Eng. 148 ( 2016 ) 839-846.

DOI: https://doi.org/10.1016/j.proeng.2016.06.627

[14] S. Mor, K. Chhoden, K. Ravindra, Application of agro-waste rice husk ash for the removal of phosphate from the wastewater, J. Clean. Prod. 129 (2016) 673-680.

DOI: https://doi.org/10.1016/j.jclepro.2016.03.088

[15] J. Liu, Y. Su, Q. Li, Q, Yue, B. Gao, Preparation of wheat straw based superabsorbent resins and their applications as adsorbents for ammonium and phosphate removal. Bioresour. Technol. 143 (2013) 32-39.

DOI: https://doi.org/10.1016/j.biortech.2013.05.100

[16] S.G. Lu, S.Q. Bai, L. Zhu, H.D. Shan, Removal mechanism of phosphate from aqueous solution by fly ash, J. Hazard. Mater. 161 (2009) 95-101.

DOI: https://doi.org/10.1016/j.jhazmat.2008.02.123

[17] Y. Jiang, T. Deng, K. Yang, H. Wang, Removal performance of phosphate from aqueous solution using a high-capacity sewage sludge-based adsorbent, J. Taiwan Inst. Chem. Eng. 76 (2017) 59-64.

DOI: https://doi.org/10.1016/j.jtice.2017.04.002