Investigations on Luminescence Properties of Ce3+ Ion Doped Bismuth Borophosphate Glasses


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Bismuth borophosphate glasses containing different doping cerium oxide have been synthesized at 1200 °C by melt-quenching technique. The doping concentration of the Ce3+ was varied from 0.05 mol% to 2.0 mol%. The glass samples were characterized through optical absorption and luminescence spectral measurements. UV-visible and near infrared absorption spectra of glass samples were not observed nevertheless the absorption edge was shift to the longer wavelength. The photoluminescence and radioluminescence spectra show emission bands around 367 nm under 317 nm excitation wavelength. Also, the highest emission intensity was found at 0.5 mol% CeF3 dopant for both of photoluminescence and radioluminescence.



Edited by:

Dr. Noppakun Sanpo, Dr. Jirasak Tharajak and Dr. Paisan Kanthang




N. Chanthima et al., "Investigations on Luminescence Properties of Ce3+ Ion Doped Bismuth Borophosphate Glasses", Applied Mechanics and Materials, Vol. 879, pp. 22-26, 2018

Online since:

March 2018




* - Corresponding Author

[1] Y.N.C.R. Babu, P.S. Ramnaik, A.S. Kumar, Photoluminescence features of Ho3+ ion doped PbO-Bi2O3 borophosphate glass systems, J. Lumin. 143 (2013) 510-516.

DOI: 10.1016/j.jlumin.2013.05.023

[2] C.R. Kesavulu, H.J. Kim, S.W. Lee, J. Kaewkhao, N. Wantana, S. Kothan, S. Kaewjaeng, Influence of Er3+ ion concentration on optical and photoluminescence properties of Er3+-doped gadolinium-calcium silica borate glasses, J. Alloy. Compd. 683 (2016).

DOI: 10.1016/j.jallcom.2016.04.314

[3] F. Zaman, G. Rooh, N. Srisittipokakun, H.J. Kim , E. Kaewnuam, P. Meejitpaisan, J. Kaewkhao, Scintillation and luminescence characteristics of Ce3+ doped in Li2O-Gd2O3-BaO-B2O3 scintillating glasses, Radiat. Phys. Chem. 130 (2017) 158-163.

DOI: 10.1016/j.radphyschem.2016.08.016

[4] J. Bei, G. Qian, X. Liang, S. Yuan, Y. Yang, G. Chen, Optical properties of Ce3+ -doped oxide glasses and correlations with optical basicity, Mater. Res. Bull. 42 (2007) 1195-1200.

DOI: 10.1016/j.materresbull.2006.10.020

[5] A.D. Sontakke, J. Ueda, S. Tanabe, Effect of synthesis conditions on Ce3+ luminescence in borate glasses, J. Non Cryst. Solids. 431 (2016) 150-153.

DOI: 10.1016/j.jnoncrysol.2015.04.005

[6] J.M. Park, D.H. Ha, S. Kaewjeang, U. Maghanemi, S. Kothan, J. Kaewkhao, H.J. Kim, Luminescence properties of Ce3+ doped gadolinium-calcium silicaborate glass scintillator, Radiat. Meas. 90 (2016) 166-169.

DOI: 10.1016/j.radmeas.2015.12.028

[7] X.Y. Sun, P. Gao, Y.Q. Zheng, M. Zhang, H.S. Wu, Y. Yuan, Enhanced emission intensity of Ce3+ ions in Li2O–B2O3–Gd2O3 scintillating glasses by adding carbon and Si3N4 agent, J. Non Cryst. Solids. 422 (2015) 12-15.

[8] A.S. Kumar, T. Narendrudu, S. Suresh, M.V.S. Rao, G.C. Ram, D.K. Rao, Role of titanium ions on the physical and structural properties of calcium zinc bismuth phosphate glass ceramics, J. non-cryst. Solids. 434 (2016) 62-70.

DOI: 10.1016/j.jnoncrysol.2015.12.010

[9] N. Vedeanu, O. Cozar, R. Stanescu, I.B. Cozar, I. Ardelean, Structural investigation of new vanadium-bismuth-phosphate glasses by IR and ESR spectroscopy, J. Mol. Struct. 1044 (2013) 323-327.

DOI: 10.1016/j.molstruc.2013.01.078

[10] P.S. Rao, Ch. Rajyasree, A.R. Babu, P.M.V. Teja, D.K. Rao, Effect of Bi2O3 proportion on physical, structural and electrical properties of zinc bismuth phosphate glasses J. non-cryst. Solids. 357 (2011) 3585-3591.

DOI: 10.1016/j.jnoncrysol.2011.07.010

[11] P.S. Rao, P.R. Babu, R. Vijay, T. Narendrudu, N. Veeraiah, D.K. Rao, Spectroscopic and dielectric response of zinc bismuth phosphate glasses as a function of chromium content, Mater. Res. Bull. 57 (2014) 58-66.

DOI: 10.1016/j.materresbull.2014.05.030

[12] H.A. Saudi, A.G. Mostafa, N. Sheta, S.U.E. Kameesy, H.A. Sallam, The structural properties of CdO-Bi2O3 borophosphate glass system containing Fe2O3 and its role in attenuating neutrons and gamma rays, Phys. B. 406 (2011) 4001-4006.

DOI: 10.1016/j.physb.2011.06.038

[13] J.W. Lim, M.L. Schmitt, R.K. Brow, S.W. Yung, Properties and structures of tin borophosphate glasses, J. non-cryst. Solids. 356 (2010) 1379-1384.

DOI: 10.1016/j.jnoncrysol.2010.02.019

[14] R.K. Brow, An XPS study of oxygen bonding in zinc phosphate and zinc borophosphate glasses, J. non-cryst. Solids. 194 (1996) 267-273.

DOI: 10.1016/0022-3093(95)00500-5

[15] Y.N.C.R. Babu, P.S.R. Naik, K.V. Kumar, N.R. Kumar, A.S. Kumar, Spectral investigations of Sm3+ doped lead bismuth magnesium borophosphate glasses, J. Quant. Spectrosc. Ra. 113 (2012) 1669-1675.

DOI: 10.1016/j.jqsrt.2012.03.034

[16] M. Ayvacikli, A. Ege, N. Can, Radioluminescence of SrAl2O4: Ln3+ (Ln = Eu, Sm, Dy) phosphor ceramic, Opt. Mater. 34 (2011) 138-142.

DOI: 10.1016/j.optmat.2011.07.023

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