Nickel Phthalocyanine Complex Encapsulated into Nanopores of Faujasite Zeolite
Nickel(II) phthalocyanine complexes encapsulated in X-type Zeolite were constructed by the ‘Ship-in-bottle’ synthesis, whose characterizations were performed by fluorescent X-ray, UV-vis, reflectance, and ESR spectroscopic methods. UV-vis and Reflectance spectra of NiPc-Na+-X suggested that the Pc ring was synthesized. Solid state ESR spectrum of NiPc-Na+-X gave characteristic pattern for organic radical species. Catalytic oxidation reactivity of the NiPc-Na+-X in homogeneous reaction have been studied for organic substrate in the presence of H2O2.
Masayuki Nogami, Riguang Jin, Toshihiro Kasuga and Wantai Yang
N. Ohata et al., "Nickel Phthalocyanine Complex Encapsulated into Nanopores of Faujasite Zeolite", Advanced Materials Research, Vols. 11-12, pp. 281-284, 2006