Surface Morphological Study of Lead Titanate Thin Films Prepared on ITO Glass Substrate


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The most important thing in preparing thin films ceramic material such lead titanate, PbTiO3 is the behavioral of microstructural changes due to the applying heat treatment during crystallization process. In general, the imperfection of PbTiO3 surface morphology such as porosity, grain boundaries, existence of microcrack films, films out-diffusion and others are caused by this factor, heat transfer element and found very interesting to be discussed towards next electrical characterization. However, the present study only focuses on the surface morphology of PbTiO3 thin films that observed by both field emissions scanning electron microscopy (FESEM) and atomic force microscopy (AFM). The details of measurement for observation will be explained later. The preparation of PbTiO3 thin films were done trough simple sol-gel spin coating method deposited on ITO coated glass substrate.



Edited by:

Mohamad Hafiz Mamat, Tetsuo Soga and Mohamad Rusop Mahmood




N. Zainal and M. Rusop, "Surface Morphological Study of Lead Titanate Thin Films Prepared on ITO Glass Substrate", Advanced Materials Research, Vol. 1109, pp. 466-470, 2015

Online since:

June 2015




* - Corresponding Author

[1] S. Kim, M. Jun and S. Hwang, Preparation of undoped lead titanate ceramics via sol – gel processing, J. Am. Ceram. Soc. 96 (1999) 289-296.


[2] A. Pignolet, P. E. Schmid, L. Wang and F. Levy, Structure and electrical properties of sputtered lead titanate thin films, J. Phys. D Appl. Phys. 619 (1991) 58–61.


[3] C. H. Wang and D. J. Choi, Effect of the Pb / Ti source ratio on the crystallization of pbtio 3 thin films grown by metalorganic chemical vapor deposition at low temperature of 400˚C, J. Am. Ceram. Soc. 13 (2001) 207–213.


[4] T. Morita and Y. Cho, Hydrothermally deposited PbTiO3 epitaxial thin film, J. Korean Phys. Soc. 46 (2005) 10–14.

[5] R. A. Bakar and M. Rusop, Electrical properties of sol-gel derived lead titanate thin films by dip coating technique, 2010 Int. Conf. Electron. Devices, Syst. Appl. (2010) 415–417.


[6] D. G. Wang, C. Z. Chen, J. Ma and T. H. Liu, Lead-based titanate ferroelectric thin films fabricated by a sol- gel technique, Appl. Surf. Sci. 255 (2008) 1637-1645.


[7] C.Y. Lee, N.H. Tai, H.S. Sheu, H.T. Chiu and S.H. Hsieh, The formation of perovskite PbTiO3 powders by sol–gel process, Mater. Chem. Phys. 97(2006) 468-471.


[8] T. Ohno, H. Suzuki, D. Fu, M. Takahashi, T. Ota and K. Ishikawa, Effect of rapid thermal annealing on residual stress in lead titanate thin film by chemical solution deposition, Ceram. Int. 30 (2004) 1487-1491.


[9] C. Jégou, L. Michalas, T. Maroutian, G. Agnus, M. Koutsoureli, G. Papaioannou, L. Largeau, D. Troadec, A. Leuliet, P. Aubert and P. Lecoeur, Temperature dependence of the conduction mechanisms through a Pb(Zr, Ti)O3 thin film, Thin Solid Films 563 (2014).


[10] J. Moon, J. A. Kerchner, J. Lebleu, A. A. Morrone and J. H. Adair, Oriented lead titanate film growth at lower temperatures by the sol-gel method on particle-seeded substrates, J. Am. Ceram. Soc. 80 (1997) 2613–2623.


[11] D. Bao, X. Yao, N. Wakiya, K. Shinozaki and N. Mizutani, Structural , dielectric , and ferroelectric properties of PbTiO3 thin films by a simple sol-gel technique, Mater. Sci. Eng. B 94 (2002) 269-274.


[12] W. L. Chang and J. L. He, Influence of the lead source materials on the microstructure and ferroelectric properties of PZT films sputter-deposited using lead and lead oxide, J. Electroceramics 13 (2004) 35-39.


[13] J. Yang, W. S. Kim and H. Park, The effect of excess Pb content on the crystallization and electrical properties in sol-gel derived Pb(Zr0. 4, Ti0. 6)O3 thin films, Thin Solid Films 377–378 (2000) 739-744.