In this research, NaA zeolite samples were synthesized from aluminosilicate solution through hydrothermal method. The effects of different parameters such as the SiO2/Al2O3, OH-/Si and H2O/Na2O molar ratios of the initial gel solution, crystallization time and temperature on the crystallinity and morphology of the synthesized zeolites were investigated. The final products were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM) and laser particle size analyzer. The experiment results indicated that the SiO2/Al2O3 molar ratio had influence on morphology and size of the synthesized zeolites, the optimum range of SiO2/Al2O3 molar ratio for synthesizing NaA zeolite was 1.5-2. Alkalinity (OH-/Si and H2O/Na2O molar ratio) had a significant effect on particle sizes of the synthesized zeolites, the higher the alkalinity, the smaller the crystal particle size. In addition, it was found that crystallization temperature during hydrothermal treatment played an important role in reducing the over all reaction time. The crystallization time had effect on the crystallinity of the synthesized zeolites. Finally, the optimum synthesis parameters can be proposed in order to synthesize NaA zeolite with desirable particle size, crystallinity and morphology.