Vanadium is an important alloying elements and structural materials, a large part of vanadium was extracted from stone coal. The resources of stone coal are very rich in China. It's an important development direction to extract vanadium in stone coal. The stone coal in Shaanxi Province Shanyang County has been studied. Vanadium was extracted by HDEHP in this experiment, which is in the sulfuric acid solution leaching system. The paper researched the influence of concentration of di(2-ethylhexyl) phosphate (HDEHP), pH, the extraction time, the extraction stages, the phase ratio for the extraction ratio of vanadium, the extraction capacity of organic phase and the extraction isotherm. The best technical parameters: 20% di(2-ethylhexyl) phosphate (HDEHP), TBP 5%, sulfonated kerosene 75%(volume concentration), pH=2.5, phase ratio Vo:Va=1:5 and the extraction time is 5 min, extraction of 5 stages level. The extraction ratio of vanadium is 98.57% from the solution of 2.9658 mg/ml vanadium in that technical parameter. The best stripping of vanadium process parameters: the stripping agent for 1 mol/l of sulfuric acid, phase ratio Vo: Va = 5:1, the stripping time is 5 min, the stripping of three stages. Under this condition we may strip loaded organic phase which contain the vanadium 9.0266 mg/ml, the stripping rate is 99.73%.