Synthesis, Structure and Properties of Super Fine LiMn2O4


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In this paper, super fine LiMn2O4 powder was synthesized by mechanochemical method starting from Li2CO3 and Mn2O3. The structure, size and morphology of LiMn2O4 were explored with X-ray diffraction and scanning electron microscopy (SEM). The electrochemical properties of LiMn2O4 were studied in 2 mol/L (NH4)2SO4 solution. The result showed that pure spinel LiMn204 powder was prepared after 8h grinding with 3.0KW of power and the particle size was about 1µm. Cyclic vohammetry curve indicate LiMn2O4 electrode material has better capacitive performances.



Edited by:

Yiwang Bao, Li Tian and Jianghong Gong




J. Song et al., "Synthesis, Structure and Properties of Super Fine LiMn2O4", Advanced Materials Research, Vol. 177, pp. 9-11, 2011

Online since:

December 2010




[1] Y.G. Wang, Y.Y. Xia: Electrochemistry Communications. Vol. 7(2005), p.1138.

[2] J.M. Tarascon, E. Wang, F.K. Shokoohi, et al.: J. Electrochem. Soc. Vol. 138 (1991), p.2859.

[3] C. Masquelier, M. Tabuchi, K. Ado, et al.: J. Solid State Chem. Vol. 123 (1996), p.255.

[4] M.M. Thackeray, P.J. Johnson, L.A. de Picciotto, et al.: Mater. Res. Bull. Vol. 19 (1984), p.179.

[5] M.M. Thakeray, W.I.F. David, P.G. Bruce, et al.: Mater. Res. Bull. Vol. 18(1983), p.461.

[6] Y. Gao, J.R. Dahn, J. Electrochem: Soc. Vol. 143 (1996), p.100.

[7] G. Ting-Kuo Fey, C. -Z. Lu, T. Prem Kumar: J. Power Sources. Vol. 115 (2003), p.332.

[8] T. -F. Yi, J. Shu, Y. -R. Zhu, R. -S. Zhu: J. Phys. Chem. Solids. Vol. 70 (2009), p.153.

[9] W. Liu, G.C. Farrington, F. Chaput, B. Dunn: J. Electrochem. Soc. Vol. 143 (1996), p.879.

[10] H. -W. Chan, J. -G. Duh, S. -R. Sheen, et al.: Surf. Coat. Technol. Vol. 200(2005), p.1330.

[11] S. -J. Bao, Y. -Y. Liang, H. -L. Li: Mater. Lett. Vol. 59 (2005), p.3761.

[12] I. Taniguchi, N. Fukuda, M. Konarova: Powder Technol. Vol. 181 (2008), p.228.

[13] K. Miura, A. Yamada, M. Tanaka, Electrochim: Acta. Vol. 41 (1996), p.249.

[14] T.F. Yia, C.L. Hao, C.B. Yue, R.S. Zhu, J. Shu: Synthetic Metals. Vol. 159 (2009), p.1255.

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