The Comparison of Electrolysis Manganese Craft on Stainless Steel and Titanium


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In this paper, Potentiodynamic scans and Potentiostatic experiments are used to study manganese electro deposition on stainless steel and titanium substrates from simple chloride solutions with addition of ammonium chloride. The surface morphology and the crystal structure of manganese electrodeposits are analyzed by scanning electron microscope (SEM) and powder X-ray diffraction spectrometer (XRD), respectively. The comparison of electrolysis manganese craft on stainless steel and titanium, It is found that precipitation hydrogen is easier and the cell voltage is higher on stainless steel ,but there are more side reactions on titanium; The cubic crystal form manganese deposite on stainless steel and titanium, but the higher pure degree manganese can be obtained on stainless steel, the depositions on the titanium are imply impurity.



Advanced Materials Research (Volumes 194-196)

Edited by:

Jianmin Zeng, Taosen Li, Shaojian Ma, Zhengyi Jiang and Daoguo Yang




J. H. Tan et al., "The Comparison of Electrolysis Manganese Craft on Stainless Steel and Titanium", Advanced Materials Research, Vols. 194-196, pp. 275-282, 2011

Online since:

February 2011




[1] Kui Yin. Electrolytic manganese technology new progress. China manganese industry(In chinese). 1998, 16(4): 40-42.

[2] Yunmin Wang. China's manganese ore resources and electrolytic manganese technology new progress. China manganese industry(In chinese). 2004, 7, 22(3).

[3] H.H. Oaks and W.E. Bradt, Trans. Electrochem. Soc., 69, 567(1936).

[4] W.E. Bradt and H.H. Oaks, Trans. Electrochem. Soc., 71, 279 (1937).

[5] W.E. Bradt and L.R. Taylor, Trans. Electrochem. Soc., 73, 327(1938).

[6] C.G. Fink and M. Kolodney, Trans. Electrochem. Soc., 71, 287(1937).

[7] S.M. Shelton and M.B. Royer, Trans. Electrochem. Soc., 76, 447(1939).

[8] Jie Gong and Giovanni Zangari. Journal of The Electrochemical Society, 149 (4) (2002): 209-217.

[9] PingWei ,O.E. HilemanJr. ,M. -RezaBateni , XiaohuaDeng , AnthonyPetric. Surface & Coatings Technology, 201 (2007) 7739-7745.

[10] Jeng-KueiChang, Chiung-HuiHuang, Wen-TaTsai, Ming-JayDeng, I-WenSun , Po-YuChen. Electrochimica Acta , 53 (2008): 4447-4453.

[11] Prabhakar Rethinaraj J, Visvanathan S. Materials Chemistry and Physics, 21, ( 1991): 337.

[12] Olenl. Anode material or electrolytic manganese dioxide cell, US 4 744 878, (1988).

[13] Pingwei Fang. Electrolytic MnO2 with titanium alloy anode, CN 1067 455 A, (1991).

[14] Jie Du. Ionic membrane electrolytic MnO2 and Mn at the same time (In chinese). Harbin industrial university, 2007, 07.

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