Hydrothermal Preparation and Formation Mechanism of ZnSn(OH)6 Cubic Aggregates and Zn2SnO4 Octahedra

Abstract:

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ZnSn(OH)6 hierarchical cubes and Zn2SnO4 octahedra have been synthesized through a rapid, template-free, one-pot hydrothermal approach using zinc acetate, tin chloride and sodium hydroxide. ZnSn(OH)6 aggregates with cubic morphology and uniform size distribution have been successfully synthesized via aggregation-mediated crystallization. Through adjusting the hydrothermal parameters, Zn2SnO4 octahedra were obtained at a higher temperature. The formation of Zn2SnO4 octahedra undergone a transformation from ZnSn(OH)6 cubes. The as-synthesized products were characterized by powder X-ray diffraction (XRD), scanning electron microscopy (SEM) and differential scanning calorimetric analysis (DSC) and thermogravimetric analysis (TG).

Info:

Periodical:

Advanced Materials Research (Volumes 194-196)

Edited by:

Jianmin Zeng, Taosen Li, Shaojian Ma, Zhengyi Jiang and Daoguo Yang

Pages:

693-699

DOI:

10.4028/www.scientific.net/AMR.194-196.693

Citation:

L. X. Yang et al., "Hydrothermal Preparation and Formation Mechanism of ZnSn(OH)6 Cubic Aggregates and Zn2SnO4 Octahedra", Advanced Materials Research, Vols. 194-196, pp. 693-699, 2011

Online since:

February 2011

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Price:

$35.00

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