Characterization of Cellulosic Biomass Loaded with Iron and Arsenic Using High Energy X-Rays


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The biosorption of arsenic species by dried lettuce leaves (L.sativa) was investigated. Arsenic sorption, that is not effective on in natura biomass, was enhanced when the biomass was previously loaded with Fe(III). Analysis of X-ray Absorption Near-Edge Spectroscopy (XANES) spectra showed that iron was incorporated as Fe(III) and arsenic as As(V), regardless the contact with the lowest or highest valence species of these elements. The features of Extended X-ray Absorption Fine-Structure Spectroscopy (EXAFS) spectra suggest that the nearest neighboring atoms of iron ions are the same in all the samples, even in the As-Fe loaded ones. These results indicate the arsenic oxyanions as the sorbed species on the iron-loaded biomass.



Advanced Materials Research (Volumes 20-21)

Edited by:

Axel Schippers, Wolfgang Sand, Franz Glombitza and Sabine Willscher




G. Cordeiro Silva et al., "Characterization of Cellulosic Biomass Loaded with Iron and Arsenic Using High Energy X-Rays", Advanced Materials Research, Vols. 20-21, pp. 643-646, 2007

Online since:

July 2007




[1] A. C. Q. Ladeira and V. S. T. Ciminelli: Water Res. Vol. 38 (2004) p.20087.

[2] W. Zhang, P. Singh, E. Paling and S. Delides: Minerals Eng. Vol. 17 (2004), p.517.

[3] B. Volesky and G. Naja, in: Int. Biohydrometall. Symp. IBS-2005, Cape Town, South Africa (2005).

[4] R.P. Carvalho, A.M.G. Sousa, J.R. Freitas, C.P.L. Rubinger and K. Krambrock: Hydrometallurgy Vol. 71 (1-2) (2003), p.277.

[5] R.P. Carvalho, A.M.G. Sousa, G.C. Silva, K. Krambrock, M.H. Santos, W.A.A. Macedo and J.D. Ardisson, in: Int. Biohydrometall. Symp. IBS-2005, Capetown, South Africa (2005).

[6] K.J. Tiemann, J.L. Gardea-Torresdey, G. Gamez, K. Dokken, I. Cano-Aguilera, M.W. Renner and L. R. Furenlid: Environ. Sci. Technol. Vol. 34 (2000), p.693.

DOI: 10.1021/es9909071

[7] P.S. Nico, S.E. Fendorf, Y.W. Lowney, S.E. Holm and M.V. Ruby: Environ. Sci. Technol. Vol. 38 (2004), p.5253.

[8] M. Yano and K. Inoue: Analyt. Sci. Vol. 13 (Nº Supplement) (1997), p.359.

[9] J. H. Min and J.G. Hering: Water Res. Vol. 32 (5) (1998), p.1544.

[10] L. Dambies, T. Vincent and E. Guibal: Water Res. Vol. 36 (2002), p.3699.

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