Synthesis of New Benzoxazine from Cardanol-Furfural Resin and the Properties of the Corresponding Polymer

Abstract:

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A novel benzoxazine-based phenolic resin containing furan groups and long alkyl side-chain (CFB) was synthesized using cardanol-furfural resin as phenolic raw materials. The new benzoxazine-based cardanol-furfural resin derived from renewable resources was characterized by FTIR, 1H NMR spectra and Differential scanning calorimeter (DSC) etc. The thermal ring-opening reaction of the benzoxazine ring and the polymerization of the double bond were demonstrated with FTIR measurement. The thermal behavior of the cured product was also investigated with thermogravimetric analysis. The corresponding polybenzoxazine showed Tg value higher than that of polybenzoxazine prepared from cardanol, ammonia and formaldehyde. The char yield value at 800°C of the corresponding polybenzoxazine is 46.2% in N2 atmosphere. The results showed that the polybenzoxazine cured from CFB had good heat resistance and toughness.

Info:

Periodical:

Advanced Materials Research (Volumes 236-238)

Edited by:

Zhong Cao, Yinghe He, Lixian Sun and Xueqiang Cao

Pages:

317-320

DOI:

10.4028/www.scientific.net/AMR.236-238.317

Citation:

S. F. Li and W. D. Huang, "Synthesis of New Benzoxazine from Cardanol-Furfural Resin and the Properties of the Corresponding Polymer", Advanced Materials Research, Vols. 236-238, pp. 317-320, 2011

Online since:

May 2011

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$35.00

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