Synthesis,Crystal Structure and Antibacterial Activity of Nickel Complex with 5-Bromo-2- Hydroxyphenyl Ethyl Ketone Benzoyl Hydrazone

Abstract:

Article Preview

The title complex, [(C5H5N)Ni(C15H11N2O2Br)], was synthesized by the reaction of the 5-bromo-2-hydroxyphenyl ethyl ketone benzoyl hydrazone, pyridine ligand and nickel chloride in acetone. The crystal structure was determined by single-crystal X-ray diffraction. It crystallizes in the monoclinic system, space group C2/c with a = 29.507(4) Ǻ, b = 7.7738(11) Ǻ, c = 20.205(3) Ǻ, β = 126.614(2)º, Z = 8, V = 3720.1(9) Ǻ3. Its crystal structure was determined and refined to a final R= 0.0304 for 8902 independent reflections. The center nickel atom is four-coordinated. The antibacterial activity of the ligand and its complex was also studied.The antibacterial experiments indicate that they have antibacterial activity to P.aeruginosa, S.aureus, E.coli and the complex has higher activity than the ligand.

Info:

Periodical:

Advanced Materials Research (Volumes 239-242)

Edited by:

Zhong Cao, Xueqiang Cao, Lixian Sun, Yinghe He

Pages:

2153-2157

DOI:

10.4028/www.scientific.net/AMR.239-242.2153

Citation:

C. Z. Zheng et al., "Synthesis,Crystal Structure and Antibacterial Activity of Nickel Complex with 5-Bromo-2- Hydroxyphenyl Ethyl Ketone Benzoyl Hydrazone", Advanced Materials Research, Vols. 239-242, pp. 2153-2157, 2011

Online since:

May 2011

Export:

Price:

$35.00

[1] L. Pellerito, L. Nagy: Coord. Chem. Rev Vol. 224 (2002), p.111.

[2] P. Cheng, D.Z. Liao, S.P. Yan, Z.H. Jiang, G.L. Wang, X.K. Yao, H.G. Wang: Inorg. Chim. Acta Vol. 248 (1996), p.135.

[3] H. Sur: Acta. Crystallogr C49 (1993), p.870.

[4] Y.X. Ma, Z.Q. Ma, G. Zhao, Y. Ma, M. Yang: Polyhedron Vol. 8 (1989), p.2105.

[5] S.X. Liu, S. Gao: Polyhedron Vol. 17 (1998), p.81.

[6] S. Gao, Z.Q. Weng, S.X. Liu: Polyhedron Vol. 7 (1998), p.3595.

[7] N.K. Lokanath, M.A. Sridhar, H.S. Prasad, H.S. Nagaraja, P.M. Rao: Acta. Crystallogr C54 (1998), p.669.

[8] P. Domiano, A. Musatti, M. Nardelli, C.J. Pellizzi: Chem. Soc. Dalton. Trans (1975), p.295.

[9] K.C. Joshi, R. Bohra, B.S. Joshi: Inorg. Chem Vol. 31 (1992), p.598.

[10] D.X. West, Y.H. Yang, T.L. Klein, K.I. Goldberg, A.E. Liberta: Polyhedron Vol. 14 (1995), p.3051.

[11] C.J. Fang, C.Y. Duan, C. He, G. Han, Q.J. Meng: New. J. Chem Vol. 24 (2000), p.697.

[12] Z.H. Liu, C.Y. Duan, J.H. Li, Y.J. Liu, Y.H. Mei, X.Z. You: New. J. Chem: Vol. 24 (2000), p.1057.

[13] H. Hassan, R.R. Ali, K.A. Mahmood, G. Khaled, E. Hadi, D. Marzieh: J. Chem. Crystallogr Vol. 40 (2010), p.48.

[14] A.D. John: Lang's Handbook of Chemistry (1998), p.39.

[15] S.L. Liu, J.F. Dai, Y. Chen, G.B. Cao, H.W. Liu: Chin. J. Org. Chem Vol. 24 (2004), p.1583.

[16] Y.X. Ma, Y.H. Fan, D.S. Wang: Chin. J. Jinan University Vol. 17 (2003), p.292.

In order to see related information, you need to Login.