Research on Grafted Chitosan in Heterogeneous System
With phthalic anhydride, urea, metallic salt and ammonium molybdate as raw materials, Cobalt metal phthalocyanines is prepared by solid-phase method, and the cobalt metal phthalocyanine is modified by the shun dl-aspartic acid anhydride. In the homogeneous conditions, the effects of the reaction temperature, the reaction time, phthalocyanine dosage and initiator dosage are studied. The experimental results show that the grafting polymerization products with the highest grafted rate can be prepared under the optimal experimental conditions, which are found to be 60°C for the temperature, 3h for the reaction time, 0.08g for the potassium persulfate and sodium thiosulfate. The product is analyzed by means of IR, the results show that the chitosan is grafted successfully, and the reaction may occurs on the amino and the hydroxyl of chitosan.
Zhong Cao, Xueqiang Cao, Lixian Sun, Yinghe He
J. Q. Xue et al., "Research on Grafted Chitosan in Heterogeneous System", Advanced Materials Research, Vols. 239-242, pp. 3275-3278, 2011