Catalytic Decomposition Kinetics and Mechanism of Hydrogen Peroxide by Modified Activated Carbon


Article Preview

Modified activated carbon composites were prepared and their catalytic properties were evaluated in the H2O2 decomposition. Activated carbon alone showed very low activities compared to iron and manganese oxides / activated carbon composites, suggesting that the presence of Fe and Mn in the oxide plays an important role for the activation of H2O2. The presence of Mn in the composite structure produced a remarkable increase in the reactivity. The obtained results showed that the peroxide decomposition catalyzed by GACFM met pseudo-first-order kinetic and the maximum OH· production was on GACF1M3.The decomposition mechanism of H2O2 was analyzed in detail.



Advanced Materials Research (Volumes 243-249)

Edited by:

Chaohe Chen, Yong Huang and Guangfan Li






Z. Z. Liu et al., "Catalytic Decomposition Kinetics and Mechanism of Hydrogen Peroxide by Modified Activated Carbon", Advanced Materials Research, Vols. 243-249, pp. 4860-4863, 2011

Online since:

May 2011




[1] T. Zhoua, Y. Z. Li, J. Ji,. Separation and Purification Technology, Vol. 62 (2008), p.551.

[2] R.C.C. Costa, M.F.F. Lelis, L.C.A. Oliveira. J. Hazard. Mater. , B Vol. 129 (2006), p.171.

[3] A. Cuzzola, M. Bernini, P.A. Salvadori. Appl. Catal. B: Environ. , Vol. 36 (2002), p.231.

[4] F.R. Reinoso. Carbon, Vol. 36 (1998), p.159.

[5] C.S. Castro. J. Hazard. Mater., , doi: 10. 1016 /j. jhazma t . 2008. 08. 066.

[6] L.C.A. Oliveir, R.V.R.A. Rios, J.D. Fabris et al. Carbon , Vol. 40 (2002), p.2177.

[7] S. Baup, C. Jaffre, D. Wolbert. Adsorption, Vol. 6 (2000), p.219.

[8] I.A. Garner, I.A. W. Craik, R. Kirkwood. J. Chem. Technol. Biotechnol., Vol. 76 (2001) , p.932.

[9] Z.Z. Liu, H.P. Deng, ICAMMP 2010. Materials Processing Technologies.

[10] L Y ., Wu. 2007. Xiangtan University.

[11] N. D. Zhang, W. Zheng. Journal of Instrumental Analysis. Vol. 21(2002), p.36.

[12] Q. Li, J. P. Zhai, W.Y. Zhang, et al. J. Hazard. Mater. Vol. 141(2007), p.163.

[13] Z.Z. Liu, H.P. Deng, J. Zhan, X P. Wang. Environmental Science , Vol. 30(2009), p.780.

[14] A. Georgi, F. Kopinke. Appl. Catal., Vol. 58(2005), p.9.

[15] M. Kimura, I. Miyamoto. Chem. Soc. Jpn. Vol. 67 (1994) , p.2357.

[16] T.L.P. Dantas, V.P. Mendonça, H.J. José : Chemical Engineering Journal, Vol. 118( 2004) p.77.

[17] R.C. Costa, M.F. Lelis, L.C.A. Oliveira. Catal. Commun. Vol. 4(2003), p.525.

In order to see related information, you need to Login.