AC Impedance Behaviors of Ti-Zr Binary Alloys for Biomaterials


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In this study, AC impedance behaviors of Ti-Zr binary alloys for biomaterials have been investigated using by electrochemical impedance spectroscopy. Ti-10wt%, 20wt%, 30wt%, and 40wt% Zr alloys were prepared by arc melting and homogenized for 24 hr at 1000 °C in argon atmosphere. Phase constitutions and microstructure of the specimens were conducted by using XRD, OM and SEM. The corrosion properties of the specimens were examined through potentiodynamic test (potential range of -1500 ~ 2000 mV), AC impedance spectroscopy(100kHz~10mHz) in artificial saliva solution by potentiostat (EG&G Co, PARSTAT 2273. USA). In as-cast and homogenized Ti-xZr alloys, α-phase was identified by XRD. Microstructures were changed from lamellar structure to needle-like structure as Zr content increased. From the results of polarization behavior in the Ti-xZr alloys, it was found that the corrosion resistance was increased with increasing Zr content. From results of AC impedance spectroscopy, passive film resistance value of homogenized Ti-40Zr specimen(1.60×106 Ωcm2) showed higher than that of as-cast specimen.



Advanced Materials Research (Volumes 26-28)

Edited by:

Young Won Chang, Nack J. Kim and Chong Soo Lee




M. Y. Oh et al., "AC Impedance Behaviors of Ti-Zr Binary Alloys for Biomaterials", Advanced Materials Research, Vols. 26-28, pp. 817-820, 2007

Online since:

October 2007




[1] Y.L. Zhou, M. Niinomi, T. Akahori: Mater. Sci. Eng. Vol. 384 (2004), pp.92-101.

[2] M. Aziz-Kerrzo, KG. Conroy, AM. Fenelon, ST. Farrell, CB. Breslin,: Biomaterials. Vol. 22 (2001), pp.1531-1539.

DOI: 10.1016/s0142-9612(00)00309-4

[3] Rao S, Ushida T, Tateishi T, Okazaki Y, Asao S.: Bio-med Mater. Eng. Vol. 6 (1996), p.79.

[4] Walker PR, Leblanc J, Sikorska M: Biochemistry. Vol. 28 (1990), p.3911.

[5] D. Kuroda, M. Ninomi, M. Morigana, Y. Kato, T. Yashiro: Mater. Sci. Eng. Vol. 243 (1998), pp.224-249.

[6] J. J. Park, H. C. Choe, Y. M. Ko,: Materials Science Forum, Vol. 539-543 (2007), pp.1270-1275.

[7] HA. Luckey, Jr F. Kubli: ASTM publication STP. Vol. 1-3 (1998), pp.796-800.

[8] X. P. Jiang, X. Y. Wang: Mater. Sci. A, Eng. A. Vol. 429 , pp.30-35.

[9] E. Kobayashi, T. J. Wang, H. Boi, T. Yoneyama, H. Hamanaka: Mater. Sci. Vol. 9 Revised version: October 2007 Fig. 6. SEM micrographs of surface for as-cast and homogenized Ti-xZr alloys after potentiodynamic test in artificial saliva solution at 36. 5±1 °C. (a) Ti-10Zr (b) Ti-20Zr (c) Ti-30Zr (d) Ti-40Zr As-cast Homogenized.

DOI: 10.4028/

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