Synthesis and Structural Characterization of Zn(II) Coordination Polymer Material


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In order to synthesize a new catalysis material, the title complex, [Zn(2,2’-bipyridine)(H2O)2(SO4)]n, was prepared and determined by X-ray diffraction. The results shows that the compound was crystallized in the monoclinic system, space group C2/c, with a = 15.4304(14) Å, b = 12.7150(11) Å, c = 6.7068(5) Å, β = 102.103(10)º, V = 1286.61(19) Å3, Z = 4. The geometry of Zn(II) is a distorted cis-ZnN2O4 octahedron. In the structure of the title complex, a one-dimensional chain structure is formed by hydrogen-bond.



Advanced Materials Research (Volumes 282-283)

Edited by:

Helen Zhang and David Jin




L. H. Wang "Synthesis and Structural Characterization of Zn(II) Coordination Polymer Material", Advanced Materials Research, Vols. 282-283, pp. 100-103, 2011

Online since:

July 2011





[1] D. Hagrman, R. P. Haushalter, J. Zubieta: Chem. Mater. 10 (1998), (2091).

[2] Y. Q. Zheng, J. L. Jin, Z. P. Kong: Inorg. Chem. 43 (2004), 2590.

[3] A. Moissette, Y. Batonneau, C. Bremard: J. Am. Chem. Soc. 123 (2001), 12325.

[4] G. M. Scheldrick: SHELXS-97 program for the solution of crystal structures, University of Göttingen, Germany, (1997).

[5] X. S. Tai, Y. M. Feng, F. Y. Kong, D. Q. Wang, M. Y. Tan: Chinese J. Inorg. Chem. 24 (2008), 319.

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