Synthesis and Structural Characterization of Zn(II) Coordination Polymer Material
In order to synthesize a new catalysis material, the title complex, [Zn(2,2’-bipyridine)(H2O)2(SO4)]n, was prepared and determined by X-ray diffraction. The results shows that the compound was crystallized in the monoclinic system, space group C2/c, with a = 15.4304(14) Å, b = 12.7150(11) Å, c = 6.7068(5) Å, β = 102.103(10)º, V = 1286.61(19) Å3, Z = 4. The geometry of Zn(II) is a distorted cis-ZnN2O4 octahedron. In the structure of the title complex, a one-dimensional chain structure is formed by hydrogen-bond.
Helen Zhang and David Jin
L. H. Wang "Synthesis and Structural Characterization of Zn(II) Coordination Polymer Material", Advanced Materials Research, Vols. 282-283, pp. 100-103, 2011