Synthesis and Characterization of Chiral Poly(Amide-Imide) Containing L-Alanine

Abstract:

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A novel chiral poly(amide imide) containing L-alanine was synthesized by direct polycondensation reaction of newly synthesized N,N’-(4,4’-diphthaloyl)-bis-L-alanine diacid with 4,4’-diaminodiphenyl ether in a medium consisting of N-methyl-2-pyrrolidone (NMP), triphenylphosphite (TPP), calcium chloride (CaCl2), and pyridine. The new chiral diimide-diacid monomer was synthesized by direct reaction of 3,3’-4,4’-Biphenyl tetracarboxylic acid dianhydride with L-alanine in acetic acid under refluxing conditions. The resulting compounds were obtained in quantitative yields and high purity. The synthetic diacid monomer was characterized by elemental analysis, 1H-NMR spectroscopy, FT-IR techniques and specific rotation, the obtained polymer was characterized by FTIR techniques, specific rotation and solubility testing.

Info:

Periodical:

Advanced Materials Research (Volumes 282-283)

Edited by:

Helen Zhang and David Jin

Pages:

116-119

DOI:

10.4028/www.scientific.net/AMR.282-283.116

Citation:

Z. Y. Yang et al., "Synthesis and Characterization of Chiral Poly(Amide-Imide) Containing L-Alanine", Advanced Materials Research, Vols. 282-283, pp. 116-119, 2011

Online since:

July 2011

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$35.00

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