Synthesis and Characterization of Novel Functional Polymers from Hemicelluloses

Abstract:

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Hemicellulose isolated from DmM was converted to novel functional biopolymers by maleylation using maleic anhydride as reactant and LiOH as catalyst. The reaction was performed under various temperatures, times, and the amounts of catalyst and maleic anhydride on the degree substitution (DS) of products were discussed. Comparison of the reaction in different media was discussed in detail. The product had the maximum degree of substitution (DS) of 0.75. Novel functional polymers containing with carbon-carbon double bond and carboxyl groups could be confirmed by 13C NMR spectroscopy. The behavior of novel hemicellulosic derivatives was monitored by means of thermogravimetry (TG) and differential thermal analysis (DTA). It was found that the products with a high DS had a lower thermal stability than the native hemicelluloses.

Info:

Periodical:

Advanced Materials Research (Volumes 295-297)

Edited by:

Pengcheng Wang, Liqun Ai, Yungang Li, Xiaoming Sang and Jinglong Bu

Pages:

64-69

DOI:

10.4028/www.scientific.net/AMR.295-297.64

Citation:

X. W. Peng et al., "Synthesis and Characterization of Novel Functional Polymers from Hemicelluloses", Advanced Materials Research, Vols. 295-297, pp. 64-69, 2011

Online since:

July 2011

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Price:

$35.00

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