An intelligent measure control system is designed to solve the problem of real-time intelligent detection of thermal defects of high voltage equipment at unmanned substations. This system uses a new method that continuous power of CC2530, a ZigBee wireless single chip, is provided by using monocrystalline silicon solar cells and thermoelectric generation modules. This method can also solve the problem that overheat faults can not be alarmed timely when efficiency of solar cells decrease during the continuous rainy days, and can realize real-time wireless detection and remote fault analysis of thermal defects of high voltage equipment. The supervisory programs of the remote PC and the upper computer are designed through VC + +.NET and the communication mode adopts C/S model based on TCP/IP protocols. The image files are saved as JPEG format by CImage class, which implements the real-time transmission of images. All the forgoing advantages provide a technical assurance to the remote and intelligent control of the heat vice of high-voltage equipment in the unmanned substations.