One-Step Synthesis of Methyl Isobutyl Ketone from Acetone Catalysed by Ni-Zirconia

Abstract:

Article Preview

The one-step synthesis of methyl isobutyl ketone from acetone (MIBK) and H2 in liquid phase was studied over Ni-zirconia catalyst prepared by precipitation. The performances of Ni/ZrO2 catalysts were evaluated by the conversion of acetone and the selectivity of MIBK. The effect of different preparation conditions such as aging temperature, calcination temperature, nickel content and reduction temperature was investigated. The results showed that high acetone conversions of up to 33% and MIBK selectivities of up to 85% were recorded at a nickel content of 13.0 wt % and the reduction temperature of 400°C.

Info:

Periodical:

Advanced Materials Research (Volumes 391-392)

Edited by:

H.M. Zhang and B. Wu

Pages:

908-911

DOI:

10.4028/www.scientific.net/AMR.391-392.908

Citation:

C. H. Du et al., "One-Step Synthesis of Methyl Isobutyl Ketone from Acetone Catalysed by Ni-Zirconia", Advanced Materials Research, Vols. 391-392, pp. 908-911, 2012

Online since:

December 2011

Export:

Price:

$35.00

[1] Y. Onoue, Y. Mizutani, S. Akiyama, Y. Izumi and Y. Watanabe: Chemtec. Vol. 7 (1977), p.36.

[2] Y.Z. Chen, C.M. Hwang and C.W. Liaw: Appl. Catal. A: Gen Vol. 169 (1998), p.207.

[3] K. Weissermel and H.J. Arpe: Industrial Organic Chemistry (VCH Publishers, USA 1997).

[4] P.P. Yang, Y.C. Shang, J. Wang, J.F. Yu and T.H. Wu: React. Kinet. Catal. Lett. Vol. 91 (2007), p.391.

[5] F. Al-Wadaani, E.F. Kozhevnikova and I.V. Kozhevnikov: J. Catal Vol. 257 (2008), p.199.

[6] R.D. Hetterley, R. Mackey, J.T.A. Jones, Y.Z. Khimyak, A.M. Fogg and I.V. Kozhevnikov: J. Catal Vol. 258 (2008), p.250.

[7] M.Z. Zhang, Y.X. Liu, X.L. Shan, N.J. Guan and K.Y. Tao: Chemical Industry and Engineering Vol. 13 (1996), p.38.

[8] A.C.C. Rodrigues, J.L.F. Monteiro and C.A. Henriques: C. R. Chimie Vol. 12 (2009), p.1296.

[9] L.Y. Zhao, G. Wang and Y.Q. Meng: Journal of Guangxi Normal University Vol. 15 (1997), p.59.

[10] T. Yamaguchi: Catal. Today Vol. 20 (1994), p.199.

[11] Y.X. Liu, K.P. Sun, X.L. Xu and X.L. Wang: Catal. Commun Vol. 11 (2010), p.322.

[12] X.L. Xu, X.H. Liu, S.W. Liu and A.H. Tang, CN. Patent 1566060A (2005).

In order to see related information, you need to Login.