Preparation and Photocatalytic Activity of Sol-Gel Method Derived La Doped TiO2/ITO Photocatalytic Electrodes

Abstract:

Article Preview

La–doped TiO2 thin films were synthesized using TTIP, IPA , Acetic acid ,and La2¬O3 as precursors by sol-gel method and dip-coating method. The different molar raitos of La/Ti ( 0.025,0.050,0.075 and 0.100 ) were supported on ITO glass to product photocatalytic electrodes. The properties of both TiO2/ITO and La- TiO2/ITO photocatalytic electrodes were characterized by FE-SEM,BET and XRD. The FE-SEM and BET analytical results demonstrate that La-TiO2/ITO particles have uniform shape and small size (<10nm ) compared with TiO2/ITO. Anotherway, the XRD resultes show that when more molar raitos of La/Ti the crystallites become more percent to of rutile. The La-TiO2/ITO photocatalytic electrode with molar raito 0.05 shows the best photocatalysis with mineralization rate after four hours reaction. On this condition, different Acid Yellow 17 initial concentration and UV light intensity have been research. Applied potential 2.0V would effectively increase the decolonization rate under visible light irradiation.

Info:

Periodical:

Advanced Materials Research (Volumes 452-453)

Edited by:

Liu Pei

Pages:

486-490

Citation:

W. F. Wang et al., "Preparation and Photocatalytic Activity of Sol-Gel Method Derived La Doped TiO2/ITO Photocatalytic Electrodes", Advanced Materials Research, Vols. 452-453, pp. 486-490, 2012

Online since:

January 2012

Export:

Price:

$38.00

[1] He, C., Li, X. Z., Graham, N., and Wang, Y. : Applied Catalysis A : General, 305(2006), pp.54-63.

[2] Wu, J. C. S. and Chen, C. H. : Journal of Photochemistry and Photobiology A: Chemistry, Vol. 163(3) (2004), pp.509-515.

[3] Uzunova, M., Kostadinov, M., Georgieva, J., Dushkin, C., Todorovsky, D., Philippidis, N., Poulios, I., and Sotiropoulos, S. : Applied Catalysis B: Environmental, Vol. 73(2007), pp.23-33.

DOI: https://doi.org/10.1016/j.apcatb.2006.12.004

[4] Li, X. Z., Zhao, B. X. and Wang, P. ": Journal of Hazardous Materials, Vol. 147(2007), pp.281-287.

[5] Daneshvar, N., D. Salari and A. R. Khataee. : Photochemistry and Pohotbiology A: Chemistry, Vol. 162(2004), pp.317-322.

[6] Li, J., L. Li, L. Zheng, Y. Xian, and L. Jin : Electrochimica Acta, Vol. 51(2006), pp.4942-4949.

[7] Parida K.M., Nruparaj Sahu : Journal of Mlecular Catalysis A : Chemical, Vol. 287(2008), pp.151-158.

[8] Habibi, M. H., and Talebian, N. : Dyes and Pigments, Vol. 73(2007), pp.186-194.

[9] Habibi, M. H., Talebian, N., and Choi, J. : Thin Solid Films, Vol. 515(2006), pp.1461-1469.

[10] Muruhanandham, M. and M. Swaminathan. : Dyes and Pigments, Vol. 68(2006), pp.133-142.