Discussion on the Effect Factors of the Conductivity Performance of PEO-Based Polymer Electrolyte

Abstract:

Article Preview

Polymer electrolytes since the 1970s, the PV Wright, PEO polymers and inorganic salts can form complexes with high ionic conductivity. Thereafter, on a global scale, set off a craze of the theory with solid polymer electrolyte materials research and technology development, a lot of research work has been in the field to start and made great achievements in the preparation and study of different substrate materials composite polymer electrolytes, the most promising as lithium solid electrolyte materials. The polymer matrix itself large to have a high degree of crystallinity, this is very unfavorable to ion transport, therefore, to try to expand the ion transport required for the amorphous region and increase the migration of the polymer chain, and the electrolyte conductivity the rate is not only related with the polymer matrix, but also by the factors of the salt type and concentration of organic plasticizer and nano inorganic filler types and add methods.

Info:

Periodical:

Edited by:

J.Y. Liang and D.G. Li

Pages:

22-26

DOI:

10.4028/www.scientific.net/AMR.571.22

Citation:

W. M. Wang "Discussion on the Effect Factors of the Conductivity Performance of PEO-Based Polymer Electrolyte", Advanced Materials Research, Vol. 571, pp. 22-26, 2012

Online since:

September 2012

Authors:

Export:

Price:

$35.00

[1] D.S. McLachlan, An equation for the conductivity of binary mixtures with anisotropic grain structures[J], Journal of Physics C: Solid State Physics, 1987, 20(7): 865-878.

DOI: 10.1088/0022-3719/20/7/004

[2] D.S. McLachlan, M. Blaszkiewicz, R.E. Newnham, Electrical Resistivity of Composites[J], Journal of the American Ceramic Society, 1990, 73(8): 2187-2203.

DOI: 10.1111/j.1151-2916.1990.tb07576.x

[3] D.S. McLachlan, Equations for the conductivity of macroscopic mixtures[J], Journal of Physics C: Solid State Physics, 1986, 19(9): 1339-1354.

DOI: 10.1088/0022-3719/19/9/007

[4] D.S. McLachlan, J.P. Burger, An analysis of the electrical conductivity of the two phase Pd Hx system[J], Solid State Communications, 1988, 65(2): 159-161.

DOI: 10.1016/0038-1098(88)90678-3

[5] W. Wieczorek, M. Siekierski, A description of the temperature dependence of the conductivity for composite polymeric electrolytes by effective medium theory[J], Journal of Applied Physics, 1994, 76(4): 2220-2226.

DOI: 10.1063/1.357638

[6] J.R. Stevens, W. Wieczorek, Ionically conducting polyether composites[J], Canadian Journal of Chemistry, 1996, 74(11): 2106-2113.

DOI: 10.1139/v96-239

[7] J. Przyluski, M. Siekierski, W. Wieczorek, Effective medium theory in studies of conductivity of composite polymeric electrolytes[J], Electrochimica Acta, 1995, 40(13-14): 2101-2108.

DOI: 10.1016/0013-4686(95)00147-7

[8] M. Nakamura, Conductivity for the site-percolation problem by an improved effective-medium theory[J], Phys. Rev. B 1984, 29(6) : 3691-3693.

DOI: 10.1103/physrevb.29.3691

[9] G. Tammann and W. Hesse, Die Abhangigkeit der Viscositat von der Temperatur bie unterkuhlten Flussigkeiten[J], Z. Anorg. Allg. Chem., 1926, 156(1): 245-257.

DOI: 10.1002/zaac.19261560121

[10] G.S. Fulcher, Analysis of recent measurements of the viscosity of glasses[J], Journal of the American Ceramic Society, 1925, 8: 339-355.

[11] G. J. Dienes and A. C. Damask, Radiation Enhanced Diffusion in Solids[J], Journal of Applied Physics, 1958, 29(12): 1713-1721.

DOI: 10.1063/1.1723032

[12] A.S. Nowick, W-K Lee, H. Jain, Survey and interpretation of pre-exponentials of conductivity, Solid State Ionics, 1988, 28-30: 89-94.

DOI: 10.1016/s0167-2738(88)80013-4

[13] W. Wieczorek, K. Such, J. Plocharski, J. Przyluski, in: B. Scrosati (Ed. ), Proceedings of the Second InternationalSymposium on Polymer Electrolytes, Elsevier, London, 1990, p.339.

[14] W. Wieczorek, Entropy effects on conductivity of the blend-based and composite polymer solid electrolytes[J], Solid State Ionics, 1992, 53-56: 1064-1070.

DOI: 10.1016/0167-2738(92)90291-v

[15] W. Wieczorek, Temperature dependence of conductivity of mixed-phase composite polymer solid electrolytes[J], Materials Science and Engineering: B, 1992, 15(2): 108-114.

DOI: 10.1016/0921-5107(92)90041-7

[16] S. A. Mohamad, M. H. Ali, R. Yahya, Z. A. Ibrahim et al., Photovoltaic activity in a ZnSe/PEO–chitosan blend electrolyte junction[J], Ionics, 2007, 13(4) : 235-240.

DOI: 10.1007/s11581-007-0099-6

[17] H. Zhang, J. Wang, X. Xuan, K. Zhuo, FT-IR studies on interactions of AlCl3 with PEO–NaSCN polymer electrolytes[J], Electrochimica Acta 2006, 51(16): 3244-3248.

DOI: 10.1016/j.electacta.2005.09.016

[18] M.J.C. Plancha, C.M. Rangel, C.A.C. Sequeira, Pseudo-equilibrium phase diagrams for PEO–Zn salts-based electrolytes[J], Solid State Ionics, 1999, 116 (3–4): 293-300.

DOI: 10.1016/s0167-2738(98)00356-7

[19] S.J. Wen, T.J. Richardson, D.I. Ghantous, K.A. Striebel, et al., FTIR characterization of PEO+LiN(CF3SO2)2 electrolytes[J], Journal of Electroanalytical Chemistry, 1996, 408 (1–2): 113-118.

DOI: 10.1016/0022-0728(96)04536-6

[20] M. J. Reddy, T. Sreekanth, U.V.S. Rao, Study of the plasticizer effect on a (PEO+NaYF4) polymer electrolyte and its use in an electrochemical cell[J], Solid State Ionics, 1999, 126 (1–2): 55-63.

DOI: 10.1016/s0167-2738(99)00225-8

In order to see related information, you need to Login.