Study on Calcium Ions Affecting Mechanism to Collecting Quartz in the System of Dodecyl Sulphonate


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This article studied on calcium ions affecting mechanism to collecting quartz in the system of dodecyl sulphate. Studied calcium ions on Zeta potential of quartz surface and flotation behavior through flotation experiment, Zeta potential measurement, infrared spectroscopy and solution chemistry of calcium calculation. The results show that the ability of collecting quartz by anionic collector dodecyl sulphate is weak within pH range of 4-14, and basically can be seen cannot collect quartz. When adding calcium ions, the capacity of collecting quartz increases significantly. By Zeta potential of quartz surface, when pH>2, Zeta potential of the quartz surface shows negative charge, is not conducive to the adsorption of the anionic collector dodecyl sulphate. When adding calcium ions, Zeta potential increases significantly, and at pH = 10, Zeta potential begin to rise sharply, at this point, the concentration of Ca(OH)+ in the solution composition of calcium is also started to increase, and the recovery rate of the quartz begin to increase sharply. The concentration of Ca(OH)+ is the maximum within pH=11.5-13.5, and Zeta potential of quartz surface shows positive charge, and the recovery rate of the quartz is corresponding to the maximum. So can be determined, Ca(OH)+ is the main reason of affecting Zeta potential of the quartz surface, and Ca(OH)+ is the main active ingredient that activate flotation of quartz in the system of anionic collector dodecyl sulphate.



Advanced Materials Research (Volumes 581-582)

Edited by:

Jimmy (C.M.) Kao, Wen-Pei Sung and Ran Chen




L. Z. Chen et al., "Study on Calcium Ions Affecting Mechanism to Collecting Quartz in the System of Dodecyl Sulphonate", Advanced Materials Research, Vols. 581-582, pp. 983-987, 2012

Online since:

October 2012




[1] Ren Zijie, Luo Liqun, Zhang Lingyan. Prospect and Present State of Impurities Separation from Feldspar, J. China Non-Metallic Mining Industry Herald. 2009(1) : 19-22.

[2] M León, P Martín, R Vila, J Molla,A lbarra. Neutron irradiation effects on optical absorption of KU1 and KS-4V quartz glasses and Infrasil 301, J. Fusion Engineering and Design, 2009, 84(7-11): 1174-1178.


[3] Frank Preusser, Makaiko L. Chithambo, Thomas Götte, Marco Martini, Karl Ramseyer, Emmanuel J. Sendezera, George J. Susino and Ann G. Wintle. Quartz as a natural luminescence dosimeter, J Earth-Science Reviews, 2009, 97(1-4): 184-214.


[4] Auden WH. Rock crystal. New York Review Books, New York, (2008).

[5] Hou Qinglin, Chen Linzhang, Yin Ruiming, Li Jing. Research on Flotation Separation Process of Quartz-Feldspar, J. Journal of Hunan University of Technology. 2011, 25(3) 27-30.

[6] N Harouiya, E.H. Oelkers. An experimental study of the effect of aqueous fluoride on quartz and alkali-feldspar dissolution rates, J. Chemical Geology, 2004, 205: 155-167.


[7] Yu Fushun. Current Studies of Separating Quartz Feldspar through Flotation without Fluoride, J. Conservation and Utilization of Mineral Resources, 2005 (3): 52-54.

[8] Zhang Xiongming, Guo Yinxiang, Sun Xuecheng. New Flotation Process of Quartz Sand: Separation Feldspar from Quartz in Neutral or Alkalinity Medium, J. China Non-Metallic Mining Industry Herald, 2004 (2): 28-30.

[9] Pradip, D. W. Fuerstenau. The role of inorganic and organic reagents in the flotation separation of rare-earth ores, J. International Journal of Mineral Processing, 1991, 32: 1-22.


[10] Wang Dianzuo, Hu Yuehua. The investigation of Role of Surface precipitation of meta hydroxide in flotation of quartz, J. Department of Mineral Engineering, 1990(3): 160-166.

[11] Shi Yunliang, Qiu Guanzhou, Hu Yuehua, Chen Chun. Surface Chemical Reactions in Oleate Fltation of Quartz, J. Mining and Metallurgical Engineering, 2001(3): 43-45.

[12] Cooke S R B. Trans AlME, 1949: 306-309.

[13] Wan Peng, Wang Zhonghai. Study of flotation technology of feldspar and quartz, J. Mining Engineering, 2008, 6 (2): 32-35.