Performance of Chloride Binding by Aluminate Hydrates in Cement-Based Composite Materials

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The chloride binding capacity of aluminate hydrates in cement-based composite materials is investigated. The total chloride contents and free chloride contents were analyzed by acid-soluble method and water-soluble method. The chemical interaction of chloride with the hydrates of aluminate phases in cement was also studied by X-ray diffraction. Test results show that the monosulfate hydrate has chloride binding capacities, whereas ettringite has no capacity to bind chloride. The chloride binding by monosulfate hydrate is attributed to the formation of Friedel’s salt and Kuzel’s salt by the ion exchange of SO42- with Cl- and the nonlinear relationship can be represented best by a Freundlich isotherm.

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Periodical:

Edited by:

B. Xu and H.Y. Li

Pages:

211-214

Citation:

M. F. Gou and X. M. Guan, "Performance of Chloride Binding by Aluminate Hydrates in Cement-Based Composite Materials", Advanced Materials Research, Vol. 583, pp. 211-214, 2012

Online since:

October 2012

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$38.00

[1] M.D.A. Thomas, R.D. Hooton, A. Scott, et al. Cement and Concrete Research Vol. 42(2012), p.1.

[2] T. Cheewaket, C. Jaturapitakkul, W. Chalee: Construction and Building Materials Vol. 24(2010), p.1352.

[3] H. Hirao, K. Yamada, H. Takahashi, et al: Journal of Advanced Concrete Technology Vol. 3 (2005), p.77.

[4] S.O. Ekolu, M.D.A. Thomas, R.D. Hooton: Cement and Concrete Research Vol. 36(2006), p.688.

[5] H. Zibara: University of Toronto, Canada, (2001).