Activation Energy of Autonomous Polymer Chains with High LCST

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A self-oscillating polymer chain consisting of N-ethylacrylamide (NEAAm) and a Ru catalyst of the BelousovZhabotinsky (BZ) reaction was prepared. The polymer chain underwent soluble-insoluble self-oscillation induced by the BZ reaction, originating from the differing solubility of the Ru moiety in the reduced and oxidized states. The amplitude of self-oscillation was small compared to that for the polymer chains prepared from N-Isopropylacrylamide (NIPAAm). The activation energy observed with the novel, NEAAm-based polymer chain was 68 kJ/mol, similar to that found with the NIPAAm-based polymer chain and normal (no Ru catalyst incorporated in the polymer) BZ reaction.

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Periodical:

Advanced Materials Research (Volumes 941-944)

Edited by:

Jingtao Han, Xianghua Liu and Zhengyi Jiang

Pages:

1212-1215

Citation:

Y. Hara "Activation Energy of Autonomous Polymer Chains with High LCST", Advanced Materials Research, Vols. 941-944, pp. 1212-1215, 2014

Online since:

June 2014

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