Residual Stress Study in Oxide Scale Obtained on High Temperature Oxidation of AISI 430 Stainless Steel


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The objective of this work was to investigate high temperature oxidation behavior of AISI 430 stainless steel, which was proposed to use as interconnector in the planar solid oxide fuel cells (SOFCs). The oxidation of the alloy has been conducted at 700°C, 800°C and 900°C for 12h-96h by thermal gravimetric analysis (TGA) system. The oxide surface morphology, cross-section microstructure and the chemical composition of the oxide scales were performed by FEG-SEM and EDX. The X-ray diffraction (XRD) was used to identify the oxide phases formed on the alloy and to determine the residual stress in the scale. It has been found that the oxide scale composed of a inner Cr2O3 layer and an outer Mn1.5Cr1.5O4 layer. The residual stresses in both oxide layers are compressive and the residual stress evolutions in the two layers are different according the oxidation temperature.



Main Theme:

Edited by:

M. François, G. Montay, B. Panicaud, D. Retraint and E. Rouhaud




N. Li et al., "Residual Stress Study in Oxide Scale Obtained on High Temperature Oxidation of AISI 430 Stainless Steel", Advanced Materials Research, Vol. 996, pp. 918-923, 2014

Online since:

August 2014


* - Corresponding Author

[1] S.J. Geng, J.H. Zhu, Promising alloys for intermediate-temperature solid oxide fuel cell interconnect application, J. Power Sources 160 (2006) 1009-1016.


[2] B. Hua, J. Pu, F.S. Lu, J.F. Zhang, B. Chi, L. Jian, Development of a Fe-Cr alloy for interconnect application in intermediate temperature solid oxide fuel cells, J. Power Sources 195 (2010) 2782-2788.


[3] V. Miguel-Pérez, A. Martínez-Amesti, M.L. Nó, A. Larrañaga, M.I. Arriortua, Oxide scale formation on different metallic interconnects for solid fuel cells, Corros. Sci. 60 (2012) 38-49.


[4] P.P. Edwars, V.L. Kuznetsov, W.I.F. David, N.P. Brandon, Hydrogen and fuel cells: Towards a sustainable energy future, Energy Policy 36 (2008) 4356–4362.


[5] J. Froitzheim, G.H. Meier, L. Niewolak, P.J. Ennis, H. Hattendorf, L. Singheiser, W.J. Quadakkers, Development of high strength ferritic steel for interconnect application in SOFCs, J. Power Sources 178 (2009) 163–173.


[6] S. Daghigh, J.L. Lebrun, A.M. Huntz, Stresses in Cr2O3 scales developed on Ni-30Cr, Trans Tech Publication, Switzerland, (1997).

[7] A.M. Huntz, C. Liu, M. Kornmeier, J.L. Lebrun, The determination of stresses during oxidation of Ni: In situ measurements by XRD at high temperature, Corros. Sci. 35 (1993) 989-997.


[8] A.M. Huntz, Stresses in NiO, Cr2O3 and Al2O3 oxide scales, Mat. Sci. Eng. A, 201 (1995) 211-228.

[9] European Standard no NF15305, Test Method for Residual Stress Analysis by X-ray Diffraction, April(2009).

[10] J. Xiao, N. Prud'homme, N. Li, V. Ji, Influence of humidity on high temperature oxidation of Inconel 600 alloy: Oxide layers and residual stress study, Applied Surface Sci. 284 (2013) 446-452.


[11] A.S. Khanna, High temperature oxidation and corrosion, ASM International, Ohio, USA, 2002. pp.109-134.

[12] P. Kofstad, High temperature corrosion, Elsevier, Essex, England, (1988).

[13] M. Palcut, L. Mikkelsen, K. Neufeld, M. Chen, R. Knibbe, P.V. Hendriksen, Corrosion stability of ferritic stainless steels for solid oxide electrolyser cell interconnects, Corros. Sci. 52 (2010) 3309-3320.


[14] W.N. Liu, X. Sun, E. Stephens, M.A. Khaleel, Life prediction of coated and uncoated metallic interconnect for solid oxide fuel cell applications, J. Power Sources 189 (2009) 1044-1050.