Bioactive Apatite-Mullite Glass-Ceramic Coatings on Titanium Substrates


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Fluorapatite-mullite glass-ceramics have been shown to be bioactive in the cerammed state and the present study examines how they may be deposited on biomedical-grade titanium alloy substrates for orthopaedic applications. A simple deposition route was used for initial application of the material in the glassy state and it was then cerammed in-situ. This cheap and non-line-of-sight route produces well adherent coatings by virtue of a reaction between the coating and substrate during the ceramming step. Several characterization techniques including DSC and XRD have been used to determine the crystallization behaviour of the glass-ceramic ex-situ and electron microscopical techniques have been used to characterize glass-ceramic microstructures and the nature of the coating-substrate interfacial region.



Edited by:







K. T. Stanton and J. F. Vanhumbeeck, "Bioactive Apatite-Mullite Glass-Ceramic Coatings on Titanium Substrates ", Advances in Science and Technology, Vol. 45, pp. 1275-1280, 2006

Online since:

October 2006




[1] N.J. Hallab, J.J. Jacobs and J.L. Katz in Biomaterials Science, 2nd Ed., B.D. Ratner, A.S. Hoffman, F.J. Schoen and J.E. Lemons Eds., Elsevier Academic Press, Amsterdam (2004) pp.527-555.

[2] W.R. Lacefield in Bioceramics, L.L. Hench and J. Wilson Eds., Vol. 1 of Advanced Series in Ceramics, World Scientific, Singapore (1993) pp.223-238.

[3] D.R. Bloyer, J.M. Gomez-Vega, E. Saiz, J.M. McNany, R.M. Cannon and A.P. Tomsia: Acta Mater., Vol. 47, No. 15 (1999) pp.4221-4224.

DOI: 10.1016/s1359-6454(99)00280-3

[4] L.L. Hench and Ö. Andersson in Bioceramics, L.L. Hench and J. Wilson Eds., Vol. 1 of Advanced Series in Ceramics, World Scientific, Singapore (1993) p.239259.

[5] C. Jana, P. Wange, G. Grimm and W. Gotz: Glastech. Ber. Glass Sci. Technol., Vol. 68 No 4 (1995) pp.117-122.

[6] D. Benjamin, Ed., Metals Handbook, Vol. 3, 9 th Ed., American Society for Metals, Metals Park, OH, USA (1980) pp.372-406.

[7] C.O. Freeman, I.M. Brook, A. Johnson. P.V. Hatton, R.G. Hill and K.T. Stanton: J. Mat. Sci: Materials in Medicine, Vol. 14, No. 11 (2003) pp.985-990.

[8] K. Stanton and R. Hill: J. Mat. Sci., Vol. 35, No. 8 (2000) p.1911-(1916).

[9] K.T. Stanton and R.G. Hill: J. Cryst. Growth, Vol. 275 (2005) pp. e2061-e2068.

[10] H.E. Kissinger: Analytical Chemistry, Vol. 29 (1957) pp.1702-1706.

[11] A. Marotta: J. Mat. Sci., Vol. 16, (1981) pp.341-344.

[12] J.M. Gomez-Vega, E. Siaz and A.P. Tomsia: J. Biomed. Mater. Res. Vol. 46, No. 4 (1999) pp.549-559.

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