Mechanical Activation as a New Method for SHS


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The use of mechanical activation (the elemental powder mixture is milled for a short time at given frequency and impact energy) as a precursor to self-propagating high-temperature synthesis (SHS) results in the formation of nanostructured porous materials. The mechanical activation step was found necessary (i) to modify the thermal parameters of the combustion front (i.e. combustion front velocity, thermal heating rate…) in the cases of Mo-Si, Fe-Al, Ni-Si (ii) to initiate a combustion front in the case of systems having a low exothermicity. Nevertheless, the control of the mechanically activated mixture characteristics and, the understanding of the mechanical activation role on the SHS parameters are essential to produce end-products with expected microstructure.



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F. Bernard et al., "Mechanical Activation as a New Method for SHS ", Advances in Science and Technology, Vol. 45, pp. 979-988, 2006

Online since:

October 2006




[1] R. Birringer, H. Gleiter. Encyclopedia of Materials Science. Ed. R.W. Cahn, Suppl. vol n°1, Pergamon Press (1988), p.339.

[2] J. Benjamin. Metall Trans 1 (1970 ), p.2934.

[3] J. Benjamin. Sci. Am. 40 (1976), p.234.

[4] Proceedings of ISMANAM, Mater. Sci. Forum, vols. 179-181 (1995), vols. 225-227 (1996), vols. 235-238 (1997), vols. 269-272 (1998).

[5] C. Suryanarayana. Progress in Mater. Sci. 46, (2001), p.1.

[6] E. Gaffet, G. Le. Caer, in: H.S. Nalwa (Ed. ), Encyclopedia of Nanoscience and Nanotechnology, American Scientific Publishers, North Lewis Way, Stevenson Ranch (2004), p.1.

[7] E. Gaffet, F. Bernard, J. -C. Niepce, F. Charlot, C. Gras, G. Le Caër, J.L. Guichard, P. Delcroix, A. Mocellin, O. Tillement. J. Mater. Chem., 9 (1999), p.305.

DOI: 10.1039/a804645j

[8] A.G. Merzhanov, V.M. Shkiro, I.P. Borovinskaya. USSR Inventor's Artificate, n°. 255221, 1967, Byull. Izobr. N°. 10, (1971).

[9] A.G. Merzhanov, V.M. Shkiro, I.P. Borovinskaya. Pat. France, 1972, n°. 2088668 ; Pat. USA, 1973 n°. 2726643 ; Pat. England, 1974, n°. 1321084 ; Pat. Japan, 1982, n°. 1098839.

[10] A.G. Merzhanov, I.P. Borovinskaya. Dolk. Akad. Nauk. SSSR, vol. 204, (1972), p.366.

[11] J.M. Lirhman, J.L. Chermant. Ann. Chem. Fr., vol. 20, (1995), p.93.

[12] Z.A. Munir. Ceram. Bull., vol. 2, (1988) p.342.

[13] M. Zeghmati, E. Duverger, E. Gaffet. Proc. CANCAM 95 - 15ème Cong. Canad. Mécan. Appl., Ed. B. Tabarrock, S. Dost. Vol. 2 (1995), p.952.

[14] F. Charlot, E. Gaffet, B. Zeghmati, F. Bernard, J.C. Niepce, Mater. Sci. Eng. A262 (1999), p.279.

[15] V. Gauthier, C. Josse, F. Bernard, E. Gaffet, J. -P. Larpin - Mat. Sci. Eng., A265 (1999), p.117.

[16] Ch Gras, D. Vrel, E. Gaffet, F. Bernard - J. All. Comp., 314 (1-2) (2001), p.240.

[17] F. Charlot, F. Bernard, E. Gaffet, D. Klein, and J.C. Niepce, Acta. Mater. 47 (2) (1999), p.619.

[18] Ch. Gras, F. Charlot, E. Gaffet, F. Bernard, J.C. Niepce, Acta. Mater. 47 (7) (1999), p.2113.

[19] V. Gauthier, F. Bernard, E. Gaffet, D. Vrel, M. Gailhanou, JP. Larpin. Intermetallics 10 (2002), p.377.

DOI: 10.1016/s0966-9795(02)00010-9

[20] J. Lagerbom, T. Tiainen, M. Lehtonen, P. Lintula. J. Mater. Sci. 34 (1999), p.1477.

[21] H. Li, J. Liu. J the Chin.I. Ch.E. 27(1) (1996), p.1.

[22] Ch. Gras, E. Gaffet, F. Bernard, J.C. Niepce - Mater. Sci. Eng. A, A264 (1999), p.94.

[23] F. Bernard, H. Souha, E. Gaffet - Mater. Sci. Eng., A284 (2000), p.301.

[24] I.J. Shon, Z.A. Munir, K. Yamazaki, and K. Shoda, J. Amer. Ceram. Soc., Vol. 79 (1996), p.1875.

[25] Z.A. Munir, I.J. Shon, and K. Yamazaki, US Patent n° 5-794113, August (1998).

[26] Z.A. Munir, F. Bernard, F. Charlot, E. Gaffet, US Patent n° 6-200515 B1, Mars (2001).

[27] N. Malhouroux-Gaffet, E. Gaffet, J. Alloys and Compd. 198 (1993), p.143.

[28] E. Gaffet, N. Malhouroux-Gaffet, J. Alloys and Compd. 205 (1994), p.27.

[29] E. Gaffet, M. Abdelllaoui, N. Malhouroux-Gaffet. Mater. Trans. JIM 36 (1995), p.198 (A version is now commercialized by Fritstch).

DOI: 10.2320/matertrans1989.36.198

[30] Y. Chen, M. Bibole, R. Le Hazif, G. Martin. Phys. Rev. B 48 (1993), p.14.

[31] F. Bernard, E. Gaffet, Int. J. SHS, 10 (2) (2001), p.109.

[32] S. Vives, E. Gaffet, C. Meunier. Mater. Sci. Eng. A 36(2) (2004), p.229.

[33] O. Boytsov, A.I. Ustinov, E. Gaffet, F. Bernard, J. All. Comp., (2006), submitted to.

[34] P. Scardi, M. Leoni, in: E.J. Mittemeijer, P. Scardi (Eds. ), Diffraction analysis of the microstructure of materials, Springer-Verlag, Berlin, Heidelberg, (2004), p.51.

[35] A. Ustinov, L. Olikhovska, N. Budarina, F. Bernard, in: E.J. Mittemeijer, P. Scardi (Eds. ), Diffraction analysis of the microstructure of materials, Springer-Verlag, Berlin, Heidelberg, (2004), p.333.

[36] H. Van Swygenhoven, A. Caro, D. Farcas, Mater. Sci. Eng. A. 309 - 310 (2001), p.440.

[37] H. Van Swygenhoven, A. Caro, D. Farcas, Scripta. Mater. 44 (2001), p.1513.

[38] S. Paris, Ph-D thesis, Université de Bourgogne (2005).

[39] D.L. Zhang, D.Y. Ying. Mater. Sci. Eng A. 301 (2001), p.90.

[40] O. Kubaschewski, IRON-binary Phase diagrams. Springer-Verlag (1986), p.5.

[41] S. Gialanella, X. Amils, M. D. Barò, P. Delcroix, G. Le Caër, L. Lutterotti S. Suriñach, Acta mater. Vol. 46, No. 9, (1998), p.3305.

DOI: 10.1016/s1359-6454(97)00484-9

[42] A. Rogachev, Kochetov, Kurbatina, Levashov, Grinchuk, Rabinovich, Sachkova, F. Bernard, Fizika Gorenya i Vzryva Journal (2005), submitted to.

[43] Y. Adda, J. Philibert. Presses Universitaires, t. II, Tab. IV (1966), p.1162.

[44] Ch. Gras, F. Bernard, E. Gaffet. Intermetallics. 14 (5) (2006), p.521.

[45] Y. Zhang, G.C. Strangle. J. Mater. Res. 10(4) (1995), p. (1992).

[46] E.M. Carillo-Heian, O.A. Graeve, A. Feng, J.A. Farghih, Z.A. Munir. J. Mater. Res. 15(4) (1999), p. (1949).

[47] J.J. Moore, H.J. Feng, Progress in Materials Science 39 (1995), p.243.

[47] J.J. Moore, H.J. Feng, Progress in Materials Science 39 (1995), p.272.

[49] S.C. Deevi, N.N. Thadhani, Mater. Sci. Eng. A 192, (1995), p.204.

[50] T.H. Song, H.L. Lee, C.H. Pai, T. Mitsuhashi, J. Mater. Sci. Lett. 14, (1995), p.1715.

[51] M.A. Nicolet, S.S. Law, G.B. Larrabee, eds. 6 (1983), p.329.

[52] Ch. Gras, N. Berstein, E. Gaffet, F. Bernard. Intermetallics 10, (2002), p.271.

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