13th International Ceramics Congress - Part D

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Authors: Jin Woong Kim, Hiromi Shima, Takashi Yamamoto, Hiroshi Funakubo, Ken Nishida
Abstract: Ba (ZrxTi1-x)O3 (BZT) films with different Zr contents were deposited on (100)MgO substrates by RF-magnetron reactive sputtering using metal targets. The BZT films epitaxially grew on MgO substrates with only (001)/(100) orientation and had a single perovskite phase. In all cases, the ratio of Ba/Ti was stoichiometry and BZT films possess a dense microstructure. The effect of Zr content on the crystal structure was studied. The grain size was decreased with increasing Zr content. The dielectric properties of the BZT films were also measured at high frequencies region. The reliability of the high-frequency dielectric properties extracted from the measured S11 reflection coefficients. The capacitance for BZT film showed little dispersion and low dielectric loss at 1-18 GHz. These results indicated that we succeeded in depositing high-quality and potential tunable ferroelectrics for high frequency applications.
Authors: Yi Da Ho, Kung Rong Chen, Cheng Liang Huang
Abstract: MgNb2O6, a well-known ceramic material with columbite crystal structure, has attracted much attention in microwave integrated circuits and optical applications due to its superior properties, such as its high dielectric constant and an optical band gap. In this work, transparent amorphous-MgNb2O6 thin films were fabricated on ITO/glass substrates using the sol-gel method. The average optical transmission percentage in the visible range (λ=400–800 nm) is over 80% for all MgNb2O6/ITO/glass samples, while the optical band gap is estimated at ~4 eV. On the other hand, the dielectric properties of the MgNb2O6 thin films were very sensitive to the annealing conditions. In this study, the dielectric constant of the films was calculated to be higher than 30 under a 100 kHz AC electric field. The effects of the annealing temperature and atmosphere on the dielectric properties of the MgNb2O6 thin films were investigated.
Authors: Lorena Pardo, Alvaro García, Klaus Brebøl, Elisa Mercadelli, Carmen Galassi
Abstract: Submicron-structured (Bi0.5Na0.5)0.94Ba0.06TiO3 (BNBT6) dense ceramics, from nanometric powder synthesized by sol gel auto-combustion at 500°C and obtained by hot-pressing (800°C-2h) and subsequent recrystallization at moderate temperature (1000-1050°C-1h), have been studied. In-situ measurements at the shear mode of electromechanical resonance of non-standard thickness-poled shear plates as a function of the temperature show higher depolarization temperature than measurements at the radial mode of thin disks. Shear mode related material coefficients are measurable up to 160°C, being k15≈30% and d15≈250 pC.N-1 at 130°C. Depolarization is a complex phenomena caused by a ferroelectric (FE) macrodomains thermal randomization and a phase transition from the field-induced FE phase to a relaxor phase. The early stage of such a transition involves a non-negligible piezoelectricity arising most probably by the percolative coexistence of ferroelectric macrodomains in the resonator under the given stress field for each resonance mode.
Authors: Xiao Wu, Mei Lin, Chi Man Lau, Kin Wing Kwok
Abstract: A sol-gel method has been utilized to prepare lead-free 2 mol% Er-doped K0.5Na0.5NbO3-xLiNbO3 (Er-KNN-xLN, x = 0, 0.08 and 0.10) ceramics. The X-ray diffraction results show that the ceramics have the perovskite structure and Er3+ ions have diffused into the host lattice. Compared to the solid-state reaction method, the sol-gel method is favor to reduce the sintering temperatures (~ 50 °C) of ceramics. Better compositional homogeneity, as well as finer and uniform grains is resulted from the sol-gel process, which have been confirmed by the scanning electron microscope images. The photoluminescence properties of ceramic bulks have been systemically studied. Under the excitation of 980 nm, the ceramics exhibit visible up-conversion green (510-570 nm) and red (640-685 nm) emissions. The emission colors of them are located in the yellowish green region. The down-conversion emissions in near-infrared (1450-1650 nm) and mid-infrared (2600-2870 nm) regions have been exhibited. The ferroelectric, dielectric and piezoelectric properties of ceramics have also been investigated. Because of the good electrical and excellent photoluminescence performances, our sol-gel-derived Er-doped KNN-LN ceramics should have great potential for multifunctional optoelectronic applications, such as optical-electro integrated materials and devices.
Authors: Micka Bah, Fabien Giovannelli, Frédéric Schoenstein, Guy Feuillard, Emmanuel Le Clezio, Isabelle Monot-Laffez
Abstract: K0.5Na0.5NbO3 (KNN) was manufactured by spark plasma sintering (SPS), which is a fast sintering method allowing to control the grain growth. Different samples of KNN are sintered with SPS at 920°C under 50 MPa for 5 minutes. High densities over than 97% are achieved. In order to make domain engineering, KNN crystals are grown by floating zone method. Stable molten zone is reached when oxygen or nitrogen gas flux is used, leading up to 50 mm length of crystals. High electromechanical coupling factor kt about 46 %, kp around 45 % and ε33S/ε0 of 253 are achieved for KNN ceramics poled at optimum electric field about 3 kV / mm. KNN crystal boule exhibits kt about 40 % against 34 % for KNN ceramic, both poled at 1 kV / mm. These results are promising to replace PZT for transducers applications.
Authors: Toshio Ogawa
Abstract: Material research and development on piezoelectric ceramics, especially lead-free ceramics, was proposed from a viewpoint of relationships between piezoelectricity and elastic constants such as Young’s modulus and Poisson’s ratio. We developed a method to be convenient to measure acoustic wave velocities by an ultrasonic thickness gauge with high-frequency. From the change in longitudinal and transvers wave velocities before and after DC poling, it was found that the ceramic bulk density was important to improve the piezoelectricity in lead-free ceramics. As a result, the candidates of lead-free ceramic compositions with higher piezoelectricity were proposed. Furthermore, the ratio of transvers wave velocity to longitudinal wave velocity was clarified to estimate compositions with higher piezoelectricity. The measurement of sound velocities was an effective method for researching and developing piezoelectric materials, and it was possible to design the material compositions of lead-free piezoelectric ceramics as well as lead-containing ceramics by the novel measuring method.
Authors: Klaus Reichmann, Michael Naderer, Jörg Albering, Franz Andreas Mautner
Abstract: Samples exhibiting substitution of Titanium in Bismuth-Sodium-Titanate (BNT) by isovalent Zirconium, Tin and Germanium (Bi0.5Na0.5Ti(1-x)DxO3 with D = Zr, Ge and Sn and x = 0.0025; 0.0050; 0.01; 0.02; 0.04; 0.08) were investigated with respect to microstructure, relative permittivity, loss factor and polarization. The substituents differ in mass, ionic radius and d-electron configuration. The shift of transitions observed in plots of permittivity and loss factor vs. temperature indicate the influence of the ionic radius. The occurrence of a pinched hysteresis loop at ambient temperature in the Sn-doped samples and the absence of any pinching in the hysteresis loops of Zr-and Ge-doped samples give rise to the assumption that this feature of polarization is connected to the ionic radius combined with the d10 electron configuration of Sn4+.
Authors: Takashi Takeo, Masato Kawaguchi, Taichi Ishihara, Toru Matsuzaki
Abstract: Recently, wireless energy transfer techniques are being developed for hybrid (HEV) or electric (EV) vehicles. However, without taking any measures, magnetic field strength around energy transfer systems that employ solenoid type antennas is known to exceed regulated values in most countries. In this study, the application of magnetic sheets, which are widely used as EMC components, is proposed to suppress the magnetic field leakage from an automobile energy transfer system and the ability of magnetic leakage suppression with the magnetic sheet has been evaluated by means of electromagnetic simulation. Through these investigations, desirable system arrangements are discussed. As a result, if combined with a metal plate, non-conductive magnetic materials having large permeability has been found to be preferable.
Authors: Maria Rita Catalano, Gugliemo Guido Condorelli, Raffaella Lo Nigro, Graziella Malandrino
Abstract: BiFeO3 films undoped and doped with Ba and/or Ti have been fabricated through Metal-Organic Chemical Vapor Deposition (MOCVD) on SrTiO3 (100), SrTiO3:Nb (100) and YSZ (100) substrates. Films have been deposited using a multi-metal source, consisting of the Bi (phenyl)3, Fe (tmhd)3, Ba (hfa)2•tetraglyme and Ti (tmhd)2(O-iPr)2 (phenyl= -C6H5, H-tmhd=2,2,6,6-tetramethyl-3,5-heptandione; O-iPr= iso-propoxide; H-hfa=1,1,1,5,5,5-hexafluoro-2,4-pentanedione; tetraglyme = CH3O(CH2CH2O)4CH3) precursor mixture. The structural and morphological characterization of films has been carried out using X-ray diffraction (XRD) and field emission scanning electron microscopy (FE-SEM). Chemical compositional studies have been performed by energy dispersive X-ray (EDX) analysis. Structural and morphological characterizations point to the formation of crystalline phases and homogeneous surfaces for both undoped and doped BiFeO3 films. Piezoresponse force microscopy (PFM) and piezoresponce force spectroscopy (PFS) have been applied to study the piezoelectric and ferroelectric properties of the films.

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