Two-Way Shape Memory Behavior of Electrospun Non-Woven Mats Prepared from Sol-Gel Crosslinked Poly(ε-Caprolactone)


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Non-woven fibrous mats based on semicrystalline networks were prepared starting from poly(ε-caprolactone) and by combining electrospinning process and sol-gel crosslinking reaction. The mats were subjected to proper thermo-mechanical cycles to investigate their two-way shape memory capabilities (i.e. the possibility to change between two distinguished shapes upon heating and cooling), and an improvement of the two-way behaviour was researched through the application of a training cycle. An ex-situ SEM analysis described the microstructural evolution accompanying the two-way shape memory cyclic response.



Edited by:

Pietro Vincenzini




S. Pandini et al., "Two-Way Shape Memory Behavior of Electrospun Non-Woven Mats Prepared from Sol-Gel Crosslinked Poly(ε-Caprolactone)", Advances in Science and Technology, Vol. 97, pp. 100-105, 2017

Online since:

October 2016




* - Corresponding Author

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