Multi-layered amorphous Si/amorphous Ge films with a periodicity of 8 to 10nm were obtained by using ultra-high vacuum evaporation techniques. The interdiffusion coefficient (table 56) for the system was determined by measuring the intensity, of the neutron (000) forward scattering satellites arising from the modulation, as a function of annealing temperature and time. The temperature dependence of the interdiffusion coefficient at temperatures of between 620 and 710K could be described by the expression:

D(cm2/s) = 0.00634 exp[-2.35(eV)/kT]

C.Janot, A.Bruson, G.Marchal: Journal de Physique, 1986, 47[10], 1751-6

 

 

 

Table 56

Diffusion in Si/Ge Films

 

T (K)

Si/Ge

D (cm2/s)

622

50/30

6.00 x 10-22

672

60/20

1.32 x 10-20

682

60/20

4.60 x 10-20

690

60/20

4.62 x 10-20

708

60/20

9.87 x 10-20

719

60/20

2.50 x 10-19