Multi-layered amorphous Si/amorphous Ge films with a periodicity of 8 to 10nm were obtained by using ultra-high vacuum evaporation techniques. The interdiffusion coefficient (table 56) for the system was determined by measuring the intensity, of the neutron (000) forward scattering satellites arising from the modulation, as a function of annealing temperature and time. The temperature dependence of the interdiffusion coefficient at temperatures of between 620 and 710K could be described by the expression:
D(cm2/s) = 0.00634 exp[-2.35(eV)/kT]
C.Janot, A.Bruson, G.Marchal: Journal de Physique, 1986, 47[10], 1751-6
Table 56
Diffusion in Si/Ge Films
T (K) | Si/Ge | D (cm2/s) |
622 | 50/30 | 6.00 x 10-22 |
672 | 60/20 | 1.32 x 10-20 |
682 | 60/20 | 4.60 x 10-20 |
690 | 60/20 | 4.62 x 10-20 |
708 | 60/20 | 9.87 x 10-20 |
719 | 60/20 | 2.50 x 10-19 |