Serial sectioning techniques were used to study the isotope effect for the diffusion of 105Ag and 111Ag in AgBr and AgBr-0.08%CdBr2 (table 1). The AgBr crystals contained about 0.1ppm of impurities. The CdBr2-doped specimens were polycrystalline, with a mean grain diameter of 4mm. The results for Cd-doped AgBr were consistent with a vacancy mechanism.

N.L.Peterson, L.W.Barr, A.D.Le Claire: Journal of Physics - C, 1973, 6[12], 2020-39

 

 

Table 1

Isotope Effect for Ag Diffusion in AgBr and AgBr-0.08%CdBr2

 

CdBr2 (mol%)

Temperature (C)

1-111D/105D

0.08%

200C

0.0142

0

175C

0.0087

0

204C

0.0079

0

248C

0.0009

0

251C

-0.0008

0

295C

0.0053

0

337C

0.0044