The self-diffusion of In and Sb was studied (tables 1 and 2) in polycrystalline films by using neutron activation tracer scanning methods. The grain boundary diffusion parameters were evaluated at temperatures ranging from 200 to 400C. The pre-exponential factor and the activation energy for In self-diffusion were 1.17 x 10-10m2/s and 0.84eV, respectively. The parameters for Sb self-diffusion were 1.32 x 10-8m2/s and 1.11eV, respectively. Both In and Sb diffused via grain boundaries within the temperature range which was studied. The grain boundary energy and its temperature dependence was also deduced (tables 3 and 4).

A.Rastogi, K.V.Reddy: Semiconductor Science and Technology, 1994, 9[11], 2067-72

 

 

Table 1

Diffusivity of In in InSb

 

 

Temperature(C)

 

D(m2/s)

 

 

218

 

2.67 x 10-19

248

7.89 x 10-19

282

2.42 x 10-18

302

4.91 x 10-18

353

1.78 x 10-17

390

4.53 x 10-17

413

7.75 x 10-17

 

 

 

Table 2

Diffusivity of Sb in InSb

 

 

Temperature(C)

 

D(m2/s)

 

 

218

 

5.15 x 10-20

248

2.41 x 10-19

256

3.44 x 10-19

282

1.09 x 10-18

310

3.34 x 10-18

350

1.34 x 10-17

 

 

 

Table 3

Grain Boundary Energies in InSb Films

 

 

Temperature(C)

 

Energy(mJ/m2)

 

 

218

 

121.02

248

120.81

282

120.90

302

121.98

353

121.57

390

122.60

413

123.33

 

 

 

 

Table 4

Grain Boundary Energies in InSb Films

 

 

Temperature(C)

 

Energy(mJ/m2)

 

 

218

 

140.59

248

140.13

256

139.80

282

139.37

310

138.70

350

137.48