The self-diffusion of In and Sb was studied (tables 1 and 2) in polycrystalline films by using neutron activation tracer scanning methods. The grain boundary diffusion parameters were evaluated at temperatures ranging from 200 to 400C. The pre-exponential factor and the activation energy for In self-diffusion were 1.17 x 10-10m2/s and 0.84eV, respectively. The parameters for Sb self-diffusion were 1.32 x 10-8m2/s and 1.11eV, respectively. Both In and Sb diffused via grain boundaries within the temperature range which was studied. The grain boundary energy and its temperature dependence was also deduced (tables 3 and 4).
A.Rastogi, K.V.Reddy: Semiconductor Science and Technology, 1994, 9[11], 2067-72
Table 1
Diffusivity of In in InSb
Temperature(C) |
D(m2/s)
|
218 |
2.67 x 10-19 |
248 | 7.89 x 10-19 |
282 | 2.42 x 10-18 |
302 | 4.91 x 10-18 |
353 | 1.78 x 10-17 |
390 | 4.53 x 10-17 |
413 | 7.75 x 10-17 |
Table 2
Diffusivity of Sb in InSb
Temperature(C) |
D(m2/s)
|
218 |
5.15 x 10-20 |
248 | 2.41 x 10-19 |
256 | 3.44 x 10-19 |
282 | 1.09 x 10-18 |
310 | 3.34 x 10-18 |
350 | 1.34 x 10-17 |
Table 3
Grain Boundary Energies in InSb Films
Temperature(C) |
Energy(mJ/m2)
|
218 |
121.02 |
248 | 120.81 |
282 | 120.90 |
302 | 121.98 |
353 | 121.57 |
390 | 122.60 |
413 | 123.33 |
Table 4
Grain Boundary Energies in InSb Films
Temperature(C) |
Energy(mJ/m2)
|
218 |
140.59 |
248 | 140.13 |
256 | 139.80 |
282 | 139.37 |
310 | 138.70 |
350 | 137.48 |