A serial sectioning technique was used to study the diffusion of 131I in material which contained about 5ppm of impurities (table 50). The I diffusion required the same activation energy as that for Cl diffusion. The data for temperatures ranging from 307 to 448C could be described by:
D (cm2/s) = 167 exp[-36.2(kcal/mol)/RT]
A.P.Batra, L.Slifkin: Journal of the Physics and Chemistry of Solids, 1969, 30[6], 1315-20
Table 50
Diffusion of 131I in AgCl
Temperature (C) | D (cm2/s) |
448.3 | 1.75 x 10-9 |
421.2 | 6.64 x 10-10 |
397.9 | 2.52 x 10-10 |
359.7 | 5.16 x 10-11 |
334.7 | 1.62 x 10-11 |
307.5 | 3.70 x 10-12 |