A capillary reservoir method was used to study diffusion in eutectic melts, with 213U as a tracer and with U concentrations of 1wt% (table 96). The data for UCl4, at temperatures ranging from 370 to 607C, could be described by:
D (cm2/s) = 1.13 x 10-3 exp[-6.3(kcal/mol)/RT]
E.Geldner, O.Knacke, F.Müller: Zeitschrift für Anorganische und Allgemeine Chemie, 1970, 372[1], 14-20
Table 96
Diffusion of UCl4 in Eutectic KCl-LiCl Melts
Temperature (C) | D (cm2/s) |
370 | 8.30 x 10-6 |
380 | 9.10 x 10-6 |
444 | 1.36 x 10-5 |
450 | 1.39 x 10-5 |
522 | 2.07 x 10-5 |
607 | 3.16 x 10-5 |